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Merck
  • First total synthesis and structural reassignment of (-)-aplysiallene.

First total synthesis and structural reassignment of (-)-aplysiallene.

Organic letters (2007-08-19)
Jian Wang, Brian L Pagenkopf
초록

The first total synthesis of (-)-aplysiallene has been completed in 16 steps and features a key sequential Mukaiyama aerobic oxidative cyclization to prepare the fused bis-THF core. The original stereochemical assignment has been revised as shown.

MATERIALS
제품 번호
브랜드
제품 설명

Sigma-Aldrich
(Triphenylphosphoranylidene)acetaldehyde, 95%