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Merck
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주요 문서

21195-U

Supelco

GC Stationary Phase

phase Polyethyleneimine, bottle of 50 g

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About This Item

UNSPSC 코드:
23151817
NACRES:
SB.54

포장

bottle of 50 g

파라미터

0-175 °C temp. range

기술

gas chromatography (GC): suitable

기질 활성군

Polyethyleneimine phase

solubility

acetone: soluble

컬럼 유형

packed GC

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일반 설명

GC methods are divided into two classes depending on the nature of stationary phases; gas-solid chromatography (GSC) and gas-liquid chromatography (GLC). GSC has solid adsorptive material and solute particles are removed from mobile phase by electrostatic forces. GLC has a thin layer of liquid coated or bonded on the surface of an inert particle or on the walls of the column where solute particles are retained in the liquid phase based on their partition coefficients.[1] The primary necessity of a stationary phase is to provide sample separation sustaining phase integrity over a reasonable period of time. It should be stable for the chemical and thermal changes. Selectivity, peak symmetry, analysis time, degree of separation, peak tailing are few parameters to consider for choosing a stationary phase.[2] Polyethyleneimine (PEI) is suitable for protein separation. It binds insistently to negative charged stationary phase.[3] It is a pseudostationary phase which is also a cationic polymer.[4]
Synthesized specifically to be purer, of narrow molecular weight range, and without trace catalysts or impurities for use as a GC stationary phase.

픽토그램

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신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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시험 성적서(COA)

Lot/Batch Number

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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

이미 열람한 고객

B Maichel et al.
Journal of chromatography. A, 853(1-2), 121-129 (1999-09-16)
The effect of methanol and acetonitrile, respectively, on the separation of neutral compounds (benzyl alcohol, phenols) is investigated in electrokinetic chromatographic (EKC) systems consisting of polyethyleneimine (PEI) as charged, polymeric, replaceable pseudostationary phase. The separation systems consist of a buffer
Barry L. Karger
High Resolution Separation and Analysis of Biological Macromolecules: Fundamentals (1996)
James P. Lodge, Jr.
Methods of Air Sampling and Analysis, 98-98 (1988)
David B. Troy, Paul Beringer
Remington: The Science and Practice of Pharmacy, 605-605 (2006)

질문

1–4 / 4 질문  
  1. What are the specifications for Product 21195-U, Polyethyleneimine?

    1 답변
    1. The polyethyleneimine, Supelco 21195-U, is made from Aldrich 181978.  Supelco purifies the PEI to use as a GC phase; it is commonly solvated with acetone for use in the manufacturing of packings for gas chromatography columns.  It exists as a thick, clear, colorless, odorless liquid at room temperature.

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  2. What is the molecular weight of Polyethyleneimine, Product 21195-U?

    1 답변
    1. The molecular weight distribution of the polyethyleneimine: average Mn ~60,000 by gel permeation chromatography (GPC), average Mw ~750,000 by light scattering (ELSD; evaporative light scattering detection).

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  3. Do you know the pKa of polyethyleneimine?

    1 답변
    1. The nitrogens in polyethyleneimine (PEI) are mainly in tertiary amines. PEI has a pKa of approximately 5.9.

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  4. What is the Department of Transportation shipping information for this product?

    1 답변
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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