239216

Calcium carbonate

ACS reagent, ≥99.0%, powder

• Linear Formula: CaCO₃
• CAS Number: 471-34-1
• Molecular Weight: 100.09
• Beilstein: 8008338
• EC Number: 207-439-9
• MDL number: MFCD00010906
• UNSPSC 코드: 12352300
• PubChem Substance ID: 329752519
• NACRES: NA.21

속성

• Grade: ACS reagent
• 분석: ≥99.0%
• 형태: powder
• 불순물: ≤0.002 meq/g water-soluble titr. base; ≤0.005% oxidizers; ≤0.01% NH₄OH pptd.; ≤0.01% insol. dil. HCl
• pH: 8
• density: 2.93 g/mL at 25 °C (lit.)
• 음이온 미량물: chloride (Cl^-): ≤0.001%; fluoride (F^-): ≤0.0015%; sulfate (SO₄^2-): ≤0.01%
• 양이온 미량물: Ba: ≤0.005%; Fe: ≤0.003%; K: ≤0.01%; Mg: ≤0.02%; NH₄⁺: ≤0.003%; Na: ≤0.1%; Sr: ≤0.1%; heavy metals: ≤0.001% (by ICP-OES)
• SMILES string: [Ca++].[O-]C([O-])=O
• InChI: 1S/CH2O3.Ca/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
• InChI key: VTYYLEPIZMXCLO-UHFFFAOYSA-L

설명

일반 설명

CaCO₃ occurs naturally as the principal constituent of limestone, marble, and chalk, which can be prepared by the precipitation from dissolved calcium hydroxide and carbon dioxide.

애플리케이션

Calcium carbonate can be used as a precursor to prepare Pd/CaCO₃, which can be used as a catalyst:

• In Miyaura-Suzuki cross-coupling reactions.
• In the ligand-free Stille cross-coupling reaction between aryl halides and tributylphenyltin to synthesize biphenyls.

It can also be used as a base in the Pd-catalyzed regioselective Heck reaction of fluorinated haloaryls with olefins to synthesize substituted olefins.

기타 정보

Go to Redi-Dri^™ Product Listing 795445

법적 정보

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: nwg
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable