추천 제품
Grade
ACS reagent
Quality Level
분석
≥97.5%
형태
crystals
불순물
≤0.004 meq/g I2 consumers
≤0.005% insolubles
무기 잔류물
≤0.025%
pH
4.5-6.0 (25 °C, 5% in H2O)
mp
152-154 °C (lit.)
음이온 미량물
chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.005%
양이온 미량물
Fe: ≤3 ppm
heavy metals (as Pb): ≤5 ppm
SMILES string
N.SC#N
InChI
1S/CHNS.H3N/c2-1-3;/h3H;1H3
InChI key
SOIFLUNRINLCBN-UHFFFAOYSA-N
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일반 설명
Ammonium thiocyanate is an inorganic salt commonly used for thiocyanation of organic compounds.
애플리케이션
Ammonium thiocyanate may be used in the synthesis of the following:
- Substituted 2-aminothiazole derivatives by reacting with -halo ketone carbonyls in the presence of N-methylimidazole.5
- Thiiranes from corresponding oxiranes in the presence of lithium tetrafluoroborate.
Applied in the formation of novel two-dimensional Cd-SCN coordination solids with unusual and tailorable, checkerboard- or herringbone-patterned structures these structures are important steps toward technologically useful materials.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1
보충제 위험성
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
Schiff-Base Metal (II) Complexes as New Catalysts in the Efficient, Mild and Regioselective Conversion of 1, 2-Epoxyethanes to 2-Hydroxyethyl Thiocyanates with Ammonium Thiocyanate.
Bulletin of the Chemical Society of Japan, 76(1), 137-142 (2003)
Conversion of epoxides to thiiranes catalyzed with TiO(TFA)2 and TiCl3(OTf) in the presence of ammonium thiocyanate or thiourea.
Synthetic Communications, 28(21), 3913-3918 (1998)
NBS or DEAD as effective reagents in α-thiocyanation of enolizable ketones with ammonium thiocyanate.
Tetrahedron Letters, 52(13), 1432-1435 (2011)
Thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and I2O5.
Synthetic Communications, 38(14), 2367-2373 (2008)
Regioselective thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and oxone.
Tetrahedron Letters, 46(35), 5831-5834 (2005)
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