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모든 사진(3)

Key Documents

221988

Sigma-Aldrich

Ammonium thiocyanate

ACS reagent, ≥97.5%

동의어(들):

Ammonium rhodanide

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About This Item

Linear Formula:
NH4SCN
CAS Number:
Molecular Weight:
76.12
Beilstein:
3595135
EC Number:
MDL number:
UNSPSC 코드:
12352300
eCl@ss:
38060604
PubChem Substance ID:
NACRES:
NB.24

Grade

ACS reagent

Quality Level

분석

≥97.5%

형태

crystals

불순물

≤0.004 meq/g I2 consumers
≤0.005% insolubles

무기 잔류물

≤0.025%

pH

4.5-6.0 (25 °C, 5% in H2O)

mp

152-154 °C (lit.)

음이온 미량물

chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.005%

양이온 미량물

Fe: ≤3 ppm
heavy metals (as Pb): ≤5 ppm

SMILES string

N.SC#N

InChI

1S/CHNS.H3N/c2-1-3;/h3H;1H3

InChI key

SOIFLUNRINLCBN-UHFFFAOYSA-N

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일반 설명

Ammonium thiocyanate is an inorganic salt commonly used for thiocyanation of organic compounds.

애플리케이션

Ammonium thiocyanate may be used in the synthesis of the following:
  • Substituted 2-aminothiazole derivatives by reacting with -halo ketone carbonyls in the presence of N-methylimidazole.5
  • Thiiranes from corresponding oxiranes in the presence of lithium tetrafluoroborate.
Applied in the formation of novel two-dimensional Cd-SCN coordination solids with unusual and tailorable, checkerboard- or herringbone-patterned structures these structures are important steps toward technologically useful materials.

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1

보충제 위험성

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Schiff-Base Metal (II) Complexes as New Catalysts in the Efficient, Mild and Regioselective Conversion of 1, 2-Epoxyethanes to 2-Hydroxyethyl Thiocyanates with Ammonium Thiocyanate.
Sharghi H and Nasseri MA.
Bulletin of the Chemical Society of Japan, 76(1), 137-142 (2003)
Conversion of epoxides to thiiranes catalyzed with TiO(TFA)2 and TiCl3(OTf) in the presence of ammonium thiocyanate or thiourea.
Iranpoor N and Zeynizadeh B.
Synthetic Communications, 28(21), 3913-3918 (1998)
NBS or DEAD as effective reagents in α-thiocyanation of enolizable ketones with ammonium thiocyanate.
Reddy BVS, et al.
Tetrahedron Letters, 52(13), 1432-1435 (2011)
Thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and I2O5.
Wu J, et al.
Synthetic Communications, 38(14), 2367-2373 (2008)
Regioselective thiocyanation of aromatic and heteroaromatic compounds using ammonium thiocyanate and oxone.
Wu G, et al.
Tetrahedron Letters, 46(35), 5831-5834 (2005)

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