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Merck
모든 사진(1)

문서

92337

Sigma-Aldrich

Bromotrimethylsilane

purum, ≥97.0% (AT)

동의어(들):

TMBS, Trimethylbromosilane, Trimethylsilyl bromide

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About This Item

Linear Formula:
(CH3)3SiBr
CAS Number:
Molecular Weight:
153.09
Beilstein:
1731135
EC Number:
MDL number:
UNSPSC 코드:
12352101
PubChem Substance ID:
NACRES:
NA.22

grade

purum

Quality Level

분석

≥97.0% (AT)

형태

liquid

포함

silver wool as stabilizer

refractive index

n20/D 1.424 (lit.)
n20/D 1.424

bp

79 °C (lit.)

density

1.16 g/mL at 25 °C (lit.)

저장 온도

2-8°C

SMILES string

C[Si](C)(C)Br

InChI

1S/C3H9BrSi/c1-5(2,3)4/h1-3H3

InChI key

IYYIVELXUANFED-UHFFFAOYSA-N

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일반 설명

Bromotrimethylsilane is used with Cl3 to catalyze the direct allylation of a variety of alcohols with allyltrimethylsilane.

애플리케이션

Bromotrimethylsilane may be used as a derivatizing reagent for the determination of alkyl lysophospholipids in cell culture media using gas chromatography technique.

기타 정보

Powerful silylating agent ; Cleavage of ethers ; Smooth cleavage of phosphonic and phosphoric alkyl esters

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

표적 기관

Respiratory system

보충제 위험성

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

10.4 °F - closed cup

Flash Point (°C)

-12 °C - closed cup

개인 보호 장비

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

J.L. Meek et al.
Journal of the American Chemical Society, 110, 2317-2317 (1988)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
C. Flann et al.
Journal of the American Chemical Society, 109, 6097-6097 (1987)
S. Hanessian et al.
Tetrahedron Letters, 25, 2515-2515 (1984)
Gas chromatographic determination of alkyl lysophospholipids after solid-phase extraction from cell culture media
Coene J, et al.
Journal of Chromatography. B, Biomedical Sciences and Applications, 612(1), 21-26 (1993)

문서

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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