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Merck
모든 사진(1)

문서

86899

Supelco

Tetrabutylammonium phosphate monobasic solution

suitable for ion pair chromatography, LiChropur, concentrate, ampule

동의어(들):

Tetrabutylammonium dihydrogen phosphate

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS Number:
Molecular Weight:
339.45
Beilstein:
5196532
MDL number:
UNSPSC 코드:
12000000
PubChem Substance ID:
NACRES:
NB.21

설명

cationic

Quality Level

형태

liquid

품질

LiChropur
ampule

포장

ampule of 25 mL

기술

ion pair chromatography: suitable

λ

in concentrate

UV 흡수

λ: 210 nm Amax: 0.05
λ: 220 nm Amax: 0.04
λ: 300 nm Amax: 0.02
λ: 500 nm Amax: 0.02

적합성

corresponds to standard for RP gradient test
corresponds to standard for filter test

저장 온도

2-8°C

SMILES string

OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1

InChI key

ARRNBPCNZJXHRJ-UHFFFAOYSA-M

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일반 설명

Concentrate for 6x1 L ready-to-use solution. Dilute contents of one ampule (~0.3 M) to 1 L with HPLC grade water to obtain a 0.005 M eluent solution.
Tetrabutylammonium dihydrogen phosphate is a quaternary ammonium salt mainly used as electrolyte.

애플리케이션

Tetrabutylammonium dihydrogen phosphate has been used as ion-pairing reagent in mobile phase for ion-pair HPLC analysis of 5′-mononucleotides from baby formulae. It may also have been used in mobile phase for HPLC analysis of blood samples to determine acetaminophen.

기타 정보

Ion-pairing reagent used in reversed phase chromatography

법적 정보

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

10 - Combustible liquids

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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문서 라이브러리 방문

The analysis of 5'-mononucleotides in infant formulae by HPLC.
Perrin, Christian, et al.
Food Chemistry, 74.2, 245-253 (2001)
K Makino et al.
Journal of chromatography, 400, 271-277 (1987-07-29)
The separation of large oligodeoxyribonucleotides, synthesized chemically and subsequently deblocked, was carried out by reversed-phase ion-pair chromatography (RP-IPC) with a linear gradient of acetonitrile concentration. It was found that tetrabutylammonium phosphate is suitable as an ion-pairing reagent and produces a
C.F. Harrington et al.
Journal of Liquid Chromatography and Related Technologies, 20, 1773-1773 (1997)
In situ gelling and mucoadhesive liquid suppository containing acetaminophen: enhanced bioavailability.
Choi, Han-Gon, Yu-Kyoung Oh, and Chong-Kook Kim.
International Journal of Pharmaceutics, 165.1, 23-32 (1998)
W.E. Ladner et al.
The Journal of Organic Chemistry, 50, 1076-1076 (1985)

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