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Merck
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문서

73970

Sigma-Aldrich

N-Methyl-N-nitroso-p-toluenesulfonamide

purum, ≥98.0% (HPLC)

동의어(들):

p-Tolylsulfomethylnitrosamide, Diazald®, Diazomethane precursor, N-Methyl-N-(p-tolylsulfonyl)nitrosamide, N-Nitroso-p-toluenesulfomethylamide, N-Nitroso-N-methyl-p-toluenesulfonamide

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About This Item

실험식(Hill 표기법):
C8H10N2O3S
CAS Number:
80-11-5
Molecular Weight:
214.24
Beilstein:
2214345
EC Number:
201-252-6
MDL number:
MFCD00002050
UNSPSC 코드:
12352102
PubChem Substance ID:
329765373
NACRES:
NA.22

grade

purum

Quality Level

100

분석

≥98.0% (HPLC)

형태

crystals

반응 적합성

reaction type: C-C Bond Formation

mp

~58 °C

저장 온도

2-8°C

SMILES string

CN(N=O)S(=O)(=O)c1ccc(C)cc1

InChI

1S/C8H10N2O3S/c1-7-3-5-8(6-4-7)14(12,13)10(2)9-11/h3-6H,1-2H3

InChI key

FFKZOUIEAHOBHW-UHFFFAOYSA-N

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저장 및 안정성

Warning: these products are subject to the Explosives Act and must be transported refrigerated - additional costs for transport will apply.

기타 정보

Preparation of diazomethane

법적 정보

Diazald is a registered trademark of Merck KGaA, Darmstadt, Germany

픽토그램

FlameExclamation mark
GHS02,GHS07

신호어

Danger

유해 및 위험 성명서

H242,H315,H317,H319,H335

Hazard Classifications

Eye Irrit. 2 - Self-react. C - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

Choose from one of the most recent versions:

시험 성적서(COA)

Lot/Batch Number
STBB0771V
STBB0771
S44441
427649/1
400220/1

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문서 라이브러리 방문

M. Hudlicky
The Journal of Organic Chemistry, 45, 5377-5377 (1980)
Th.J. De Boer et al.
Organic Syntheses, 4, 250-250 (1963)
Izabela Kania-Korwel et al.
Journal of chromatography. A, 1207(1-2), 146-154 (2008-09-02)
Several polychlorinated biphenyls (PCBs) and their hydroxylated metabolites display axial chirality. Here we describe an enantioselective, gas chromatographic separation of methylated derivatives of hydroxylated (OH-)PCB atropisomers (MeO-PCB) using a chemically bonded beta-cyclodextrin column (Chirasil-Dex). The atropisomers of several MeO-PCBs could
M Börzsönyi et al.
Neoplasma, 35(3), 257-262 (1988-01-01)
N-nitroso-N-methyl-p-toluenesulfonamide (NMTS, diazald, CAS 80-11-5) is a widely used compound for laboratory production of diazomethane. The present results showed that the noncarcinogenic NMTS reacts as a transnitrosating agent with amino nitrogen of secondary amines and amide both in vitro (human
J V Uri et al.
Acta microbiologica Hungarica, 39(3-4), 317-322 (1992-01-01)
Diazald, a chemical intermediate for the synthesis of biologically active compounds, was found to be a potent in vitro antimicrobial agent against yeasts, yeast-like and filamentous fungi as well as Gram-positive and Gram-negative bacterial strains. Its activity is not inhibited
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