44297
3-Methyl-2-butenylidene-bis(tricyclohexylphosphine)dichlororuthenium
purum, ≥98.0% (C)
동의어(들):
3-Methyl-2-butenylidene-bis(tricyclohexylphosphine)ruthenium dichloride, Dichloro(3-methyl-2-butenylidene)bis(tricyclohexylphosphine)ruthenium, Grubbs catalyst 3-methyl-2-butenylidene
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C41H74Cl2P2Ru
CAS Number:
Molecular Weight:
800.95
MDL number:
UNSPSC 코드:
12352300
grade
purum
분석
≥98.0% (C)
SMILES string
C/C(C)=C\C=[Ru](\Cl)Cl.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C4CCC(CC4)P(C5CCCCC5)C6CCCCC6
포장
Bottomless glass bottle. Contents are inside inserted fused cone.
기타 정보
Catalyst for olefin metathesis reactions; Precursor to a second-generation Grubb′s catalyst that is effective to form trisubstituted olefins
Storage Class Code
12 - Non Combustible Liquids
WGK
WGK 2
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
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J P Morgan et al.
Organic letters, 2(20), 3153-3155 (2000-09-29)
Highly active N-heterocyclic carbene-coordinated catalysts may be synthesized and used in situ, without requiring prior isolation of the catalyst. Activation of this in situ catalyst with ethereal HCl dramatically reduces the reaction times required for high conversions. A variety of
M S Sanford et al.
Journal of the American Chemical Society, 123(27), 6543-6554 (2001-07-06)
This report details the effects of ligand variation on the mechanism and activity of ruthenium-based olefin metathesis catalysts. A series of ruthenium complexes of the general formula L(PR(3))(X)(2)Ru=CHR(1) have been prepared, and the influence of the substituents L, X, R
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