추천 제품
Agency
USP/NF
reag. Ph. Eur.
Quality Level
분석
98.0-103.0%
불순물
≤1.5% insoluble in ethanol
pH
8-10 (20 °C, 5%)
mp
167-170 °C (lit.)
SMILES string
O.O.O.Cc1ccc(cc1)S(=O)(=O)N([Na])Cl
InChI
1S/C7H7ClNO2S.Na.3H2O/c1-6-2-4-7(5-3-6)12(10,11)9-8;;;;/h2-5H,1H3;;3*1H2/q-1;+1;;;
InChI key
NZYOAGBNMCVQIV-UHFFFAOYSA-N
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일반 설명
Chloramine-T trihydrate is a widely used oxidizing agent in organic synthesis. It acts as a source of halonium cation and nitrogen anion and thus acts as a base and nucleophile. Due to its reactivity with a wide range of functional groups, it is involved in different molecular transformations. It is effective in acidic, neutral, and basic conditions.
애플리케이션
Chloramine-T trihydrate can be used as:
- A reagent for chlorination in drinking water treatment.
- A dehydrogenating agent for the oxidative dehydrogenation of aromatic aldehyde phenylhydrazones to synthesize nitrile imines.
- The nitrene source for the aziridination of alkenes and the amidation of cyclic ethers.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B
보충제 위험성
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 2
Flash Point (°F)
377.6 °F - closed cup
Flash Point (°C)
192 °C - closed cup
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Choose from one of the most recent versions:
이미 열람한 고객
Chloramine-T (N-chloro-p-toluenesulfonamide sodium salt), a versatile reagent in organic synthesis and analytical chemistry: An up to date review
Journal of Saudi Chemical Society, 101416-101416 (2022)
Nitrene transfer reactions catalysed by copper (I) complexes in ionic liquid using chloramine-T
Dalton Transactions (2007)
Synthesis of 3, 4-diaryl-1-phenyl-4, 5-dihydro-1H-pyrazole-5-carbonitriles via 1, 3-dipolar cycloaddition reactions
Turkish Journal of Chemistry, 37, 853-857 (2013)
Crystal and molecular structure of chloramine-T trihydrate. Absence of a sodium-nitrogen interaction in the oxidant. N-chloro-N-sodiotoluene-p-sulfonamide.
Inorganic Chemistry, 25(22), 4057-4058 (1986)
Chloramine T and related N-halogeno-N-metallo reagents.
Chemical Reviews, 78(1), 65-87 (1978)
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