Quality Level
분석
≥99.0%
광학 순도
enantiomeric ratio: ≥97.0:3.0
반응 적합성
reaction type: click chemistry
mp
99-102 °C
작용기
amine
phenyl
SMILES string
C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5
InChI
1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
InChI key
JISGHECLGYELKD-UHFFFAOYSA-N
애플리케이션
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the asymmetric hydrovinylation of 1,3-diene.
- In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
가장 최신 버전 중 하나를 선택하세요:
Asymmetric Sequential Cu-Catalyzed 1, 6/1, 4-Conjugate Additions of Hard Nucleophiles to Cyclic Dienones: Determination of Absolute Configurations and Origins of Enantioselectivity
Chemistry?A European Journal , 23(31), 7515-7525 (2017)
Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control
Journal of the American Chemical Society, 140(31), 9868-9881 (2018)
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