1.01245

Isopentyl nitrite

extra pure stabilized with potassium carbonate

• 동의어(들): Isopentyl nitrite, iso-Amyl nitrite, iso-Pentyl nitrite, Nitrous acid isoamyl ester
• 실험식(Hill 표기법): C₅H₁₁NO₂
• CAS Number: 110-46-3
• Molecular Weight: 117.15
• MDL number: MFCD00002057
• UNSPSC 코드: 12352108
• EC 인덱스 번호: 203-770-8
• NACRES: NA.22

속성

• Quality Level: 200
• 형태: liquid
• autoignition temp.: 208 °C
• 효능: 505 mg/kg LD₅₀, oral (Rat)
• bp: 97-99 °C/1013 hPa
• 전이 온도: flash point -18 °C
• density: 0.872 g/cm³ at 20 °C
• 저장 온도: 2-8°C
• InChI: 1S/C5H11NO2/c1-5(2)3-4-8-6-7/h5H,3-4H2,1-2H3
• InChI key: OWFXIOWLTKNBAP-UHFFFAOYSA-N

설명

애플리케이션

• Deaminative coupling of benzylamines and arylboronic acids: Research demonstrated the use of isopentyl nitrite in the deaminative coupling of benzylamines and arylboronic acids, showcasing its application in creating complex molecules for pharmaceutical and chemical manufacturing processes (Sirvinskaite, Reisenbauer, and Morandi, 2023).
• Syntheses of Arylazo Phosphine Oxides and Phosphonates: Utilizing isopentyl nitrite, research facilitated the synthesis of arylazo phosphine oxides and phosphonates via N-P bond formation under blue LED light conditions, contributing to developments in organophosphorus chemistry (Shen et al., 2022).

분석 메모

Total nitrites (GC): ≥ 97.0 % (a/a)
Identity (IR-spectrum): conforms
Free acid: conforms
Density (d 20 °C/ 4 °C): 0.8720 - 0.8770
Non volatile matter: ≤ 0.04 %

안전성 정보

• 픽토그램: GHS02,GHS05,GHS07,GHS08
• 신호어: Danger
• 유해 및 위험 성명서: H225 - H302 + H332 - H314 - H317 - H341
• 예방조치 성명서: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -4.0 °F - closed cup
• Flash Point (°C): -20 °C - closed cup