923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• 동의어(들): 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• 실험식(Hill 표기법): C₄₂H₄₈Cl₂FeP₂Pd
• CAS Number: 2768152-18-5
• Molecular Weight: 847.95
• UNSPSC 코드: 12352101
• NACRES: NA.21

속성

• Quality Level: 100
• 형태: powder
• 반응 적합성: reagent type: catalyst; reaction type: Cross Couplings

설명

애플리케이션

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

기타 정보

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

안전성 정보

• 픽토그램: GHS08,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H351
• 예방조치 성명서: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable