모든 사진(1)
About This Item
실험식(Hill 표기법):
C11H19NSi
CAS Number:
Molecular Weight:
193.36
MDL number:
UNSPSC 코드:
12352005
PubChem Substance ID:
분석
95%
refractive index
n20/D 1.496
density
0.917 g/mL at 25 °C
저장 온도
2-8°C
SMILES string
CC(C)[SiH](C(C)C)c1ccccn1
InChI
1S/C11H19NSi/c1-9(2)13(10(3)4)11-7-5-6-8-12-11/h5-10,13H,1-4H3
InChI key
XPUAXJBYLPPFKA-UHFFFAOYSA-N
애플리케이션
Reagent commonly used in acyloxylation reactions
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
183.9 °F
Flash Point (°C)
84.4 °C
가장 최신 버전 중 하나를 선택하세요:
The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes
Huang, C.; et al.
Advanced Synthesis & Catalysis, 353, 1285-1305 (2011)
Natalia Chernyak et al.
Journal of the American Chemical Society, 132(24), 8270-8272 (2010-06-01)
A new general and easily installable silicon-tethered pyridyl-containing directing group (PyDipSi) that allows for highly efficient and regioselective Pd-catalyzed ortho C-H acyloxylation of arenes has been developed. It has also been demonstrated that this directing group can efficiently be removed
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