710504

Bis(4-methoxyphenyl)phosphine

• 실험식(Hill 표기법): C₁₄H₁₅O₂P
• CAS Number: 84127-04-8
• Molecular Weight: 246.24
• MDL number: MFCD15143653
• UNSPSC 코드: 12352112
• PubChem Substance ID: 329762928
• NACRES: NA.22

속성

• 양식: solid
• 반응 적합성: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reagent type: ligand
• mp: 36-40 °C
• 작용기: phosphine
• SMILES string: COc1ccc(Pc2ccc(OC)cc2)cc1
• InChI: 1S/C14H15O2P/c1-15-11-3-7-13(8-4-11)17-14-9-5-12(16-2)6-10-14/h3-10,17H,1-2H3
• InChI key: FWKICRREDMVWRF-UHFFFAOYSA-N

설명

애플리케이션

Reactant for:

• Enantioselective Ir-catalyzed hydrogenation
• Palladium-catalyzed asymmetric additions
• Alkali-metal-catalyzed addition reactions
• Preparation of different DIOP-type ligands for uses in Rh-catalyzed asymmetric hydrogenation

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H228,H315,H319,H335
• 예방조치 성명서: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point (°F): >230.0 °F - closed cup
• Flash Point (°C): > 110 °C - closed cup