678503

(+)-Ipc₂B(allyl)borane solution

1 M in pentane

• 동의어(들): (+)-Ipc₂B(allyl) solution, (+)-B-Allyldiisopinocampheylborane solution
• Linear Formula: (C₁₀H₁₇)₂BCH₂CH=CH₂
• CAS Number: 106356-53-0
• Molecular Weight: 326.37
• UNSPSC 코드: 12352002
• PubChem Substance ID: 24885431
• NACRES: NA.22

속성

• 광학 활성: [α]20/D +14°, c = 1 in pentane
• 농도: 1 M in pentane
• bp: 35-36 °C
• density: 0.735 g/mL at 25 °C
• 저장 온도: −20°C
• SMILES string: C[C@@H]1[C@H](C[C@H]2C[C@@H]1C2(C)C)B(CC=C)[C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C
• InChI: 1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m0/s1
• InChI key: ZIXZBDJFGUIKJS-AXSQLCHVSA-N

설명

일반 설명

http://www.sigmaaldrich.com/ifb/acta/v35/acta-vol35-2002.html#32

애플리케이션

This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.

기타 정보

Material may become hazy upon cooler storage, this will not affect use

Under refrigerator storage, these salt-free, Ipc₂B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.

안전성 정보

• 픽토그램: GHS02,GHS08,GHS07,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H224,H304,H315,H319,H335,H336,H411
• 예방조치 성명서: P210 - P233 - P273 - P301 + P310 - P331 - P403 + P233
• Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Central nervous system, Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -56.2 °F
• Flash Point (°C): -49 °C
• 개인 보호 장비: Eyeshields, Faceshields, Gloves