모든 사진(1)
About This Item
Linear Formula:
(C2H5O)2C6H3CO2H
CAS Number:
Molecular Weight:
210.23
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
![9-Azabicyclo[3.3.1]nonane N-oxyl 95%](/deepweb/assets/sigmaaldrich/product/structures/287/155/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf/640/e2f4a2e1-1d4e-4bed-9187-9e16d23cbbbf.png)
분석
97%
양식
solid
mp
131-135 °C (lit.)
SMILES string
CCOc1cccc(OCC)c1C(O)=O
InChI
1S/C11H14O4/c1-3-14-8-6-5-7-9(15-4-2)10(8)11(12)13/h5-7H,3-4H2,1-2H3,(H,12,13)
InChI key
XUIVSLVJEQVKLB-UHFFFAOYSA-N
일반 설명
2,6-Diethoxybenzoic acid undergoes catalytic hydrodecarboxylation in the presence of toluene/D2O to afford 2-d-1,3-diethoxybenzene.
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Gloves, type N95 (US)
가장 최신 버전 중 하나를 선택하세요:
Jing Zhang et al.
Journal of the American Chemical Society, 135(46), 17270-17273 (2013-11-01)
Through-space metal/hydrogen shift is an important strategy for transition-metal-catalyzed C-H bond activation. Here we describe the synthesis and characterization of a Rh(I) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a highly unusual 1,3-rhodium migration. This aryl-to-aryl 1,3-Rh/H shift was also
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