482358
Ferrocenium tetrafluoroborate
technical grade
동의어(들):
Bis(cyclopentadienyl)iron tetrafluoroborate, Dicyclopentadienyliron fluoborate, Dicyclopentadienyliron tetrafluoroborate
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모든 사진(2)
About This Item
실험식(Hill 표기법):
C10H10BF4Fe
CAS Number:
Molecular Weight:
272.84
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Grade
technical grade
Quality Level
반응 적합성
core: iron
reagent type: catalyst
mp
178 °C (dec.) (lit.)
SMILES string
[Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.BF4.Fe/c2*1-2-4-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1
InChI key
ZSPXIHLQPWVOQR-UHFFFAOYSA-N
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일반 설명
Ferrocenium tetrafluoroborate [FeCp2][BF4] is one of the commonly employed ferrocenium salts within chemical synthesis. Ferrocenium salts are commonly used as Lewis acid catalysts, one-electron oxidants, and electron donors.
애플리케이션
Ferrocenium tetrafluoroborate serves as:
- an oxidizing agent in the synthesis of the monocationic Co(II)complex [CpCo(azpy)]+
- a Lewis acid catalyst in epoxide ring opening and to activatethe carbonyl group for addition or cycloadditions reactions
- an oxidizing agent when used in conjuntion with a Cl-source
- a reversible redox reagent between stannole dianion and bistannole-1,2-dianion
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
가장 최신 버전 중 하나를 선택하세요:
시험 성적서(COA)
Lot/Batch Number
이미 열람한 고객
Formation of exceptionally weak C?C bonds by metal-templated pinacol coupling
Folkertsma E., et al.
Dalton Transactions, 46, 6177?6182-6177?6182 (2017)
Reversible Redox Behavior between Stannole Dianion and Bistannole-1,2-Dianion
Ryuta Haga, Masaichi Saito, and Michikazu Yoshioka
Journal of the American Chemical Society, 128(15), 4934?4935-4934?4935 (2006)
Applications of ferrocenium salts in organic synthesis
Toma S, et al.
thieme, 1683-1695 (2015)
Fe (Cp) 2BF4: An efficient Lewis acid catalyst for the aminolysis of epoxides
Yadav GD, et al.
thieme, 629-634 (2014)
Krishnan Venkatasubbaiah et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(2), 444-458 (2007-12-12)
A series of mixed-valent (MV) complexes [(FeCp)2(mu-C10H6(BPh)2)]+X ([1+]X; X=I 5, PF6, SbF6, B(C6F5)4) were prepared by oxidation of diboradiferrocene [(FeCp)2(mu-C10H6(BPh)2)] (1) with I 2, AgPF6, and AgSbF6, respectively, and through anion exchange of the I 5(-) salt with [Li(Et2O)x][B(C6F5)4] in
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