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Merck
모든 사진(1)

주요 문서

431338

Sigma-Aldrich

Ammonium cerium(IV) nitrate

99.99%

동의어(들):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
Molecular Weight:
548.22
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:

분석

99.99%

반응 적합성

reagent type: oxidant

불순물

≤0.05% insol. dil. H2SO4
<100 ppm total metallic impurities

음이온 미량물

chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤0.02%

양이온 미량물

Fe: ≤0.005%

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.

특징 및 장점

Meets ACS reagent specifications.

교체됨

제품 번호
설명
가격

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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문서 라이브러리 방문

Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
David A Evans et al.
Organic letters, 8(24), 5669-5671 (2006-11-17)
The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many
Meng Zhou et al.
Journal of the American Chemical Society, 132(36), 12550-12551 (2010-08-25)
A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation
Haizhou Sun et al.
Organic letters, 5(18), 3189-3192 (2003-08-29)
[reaction: see text] The removal of electroauxiliaries from peptide substrates with chemical oxidants has been examined as a method for inserting N-acyliminium ions into the peptides. To this end, it was found that both 4-methoxyphenyldimethylsilyl and 2,4-dimethoxyphenyldimethylsilyl electroauxiliaries were readily

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