397237

Acetanilide

zone-refined, purified by sublimation, ≥99.95%

• 동의어(들): N-Phenylacetamide
• Linear Formula: CH₃CONHC₆H₅
• CAS Number: 103-84-4
• Molecular Weight: 135.16
• Beilstein: 606468
• EC Number: 203-150-7
• MDL number: MFCD00008674
• UNSPSC 코드: 12352100
• eCl@ss: 39031308
• PubChem Substance ID: 24864695
• NACRES: NA.22

속성

• Grade: zone-refined
• vapor density: 4.65 (vs air)
• vapor pressure: 1 mmHg ( 114 °C)
• 분석: ≥99.95%
• 형태: solid
• autoignition temp.: 1004 °F
• 정제법: sublimation
• bp: 304 °C (lit.)
• mp: 113-115 °C (lit.)
• SMILES string: CC(=O)Nc1ccccc1
• InChI: 1S/C8H9NO/c1-7(10)9-8-5-3-2-4-6-8/h2-6H,1H3,(H,9,10)
• InChI key: FZERHIULMFGESH-UHFFFAOYSA-N

설명

일반 설명

Acetanilide is an aniline derivative. Crystal structure of acetanillide has been studied by X-ray diffraction. It crystallizes in orthorhombic system having space group of Pbca. Its photolysis has been studied in the presence of β-cyclodextrin (cycloheptaamylose). Aminoacetophenone derivatives are obtained by the Fries rearrangement of acetanilide in the presence zeolites Y and β.

애플리케이션

Acetanilide may be used in the synthesis of ortho-haloacetanilides via regioselective C-H functionalization/halogenation reaction in the presence of Pd(OAc)₂ and Cu(OAc)₂ catalyst. It may be used in the preparation of chlorosubstituted acetanilides.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H302
• 예방조치 성명서: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point (°F): 321.8 °F - closed cup
• Flash Point (°C): 161 °C - closed cup
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves