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Merck
모든 사진(2)

문서

374989

Sigma-Aldrich

Triisobutylamine

98%

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About This Item

Linear Formula:
[(CH3)2CHCH2]3N
CAS Number:
Molecular Weight:
185.35
Beilstein:
1698950
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

98%

refractive index

n20/D 1.423 (lit.)

bp

192-193 °C/770 mmHg (lit.)

density

0.766 g/mL at 25 °C (lit.)

SMILES string

CC(C)CN(CC(C)C)CC(C)C

InChI

1S/C12H27N/c1-10(2)7-13(8-11(3)4)9-12(5)6/h10-12H,7-9H2,1-6H3

InChI key

IIFFFBSAXDNJHX-UHFFFAOYSA-N

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일반 설명

Triisobutylamine is a sterically hindered amine. The rate constants for H-atom abstraction from triisobutylamine has been evaluated.
Triisobutylamine is an organic base. Solubility and liquid-liquid equilibria of binary mixtures of triisobutylamine and water has been evaluated.

애플리케이션

Triisobutylamine is suitable to develop second generation ionic liquid matrices for MALDI-MS of peptides, proteins and carbohydrates. It may be used in the separation of cis-fatty acid salts and and trans-fatty acid (elaidic acid) salts using a new organic solvent nanofiltration membrane based on polydicyclopentadiene. It may be used as base in the synthesis of acroyl ammonium derivatives.

픽토그램

FlameSkull and crossbonesCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point (°F)

134.6 °F - closed cup

Flash Point (°C)

57 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


시험 성적서(COA)

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문서 라이브러리 방문

이미 열람한 고객

Slide 1 of 1

1 of 1

Synthesis of a Fused ?-Lactone via Pyridine-Assisted [2+ 2] Cycloaddition.
Reddy LR and Corey EJ.
Synfacts, 06, 0550-0550 (2006)
IUPAC-NIST Solubility Data Series. 96. Amines with Water Part 2. C7-C24 Aliphatic Amines.
Goral M, et al.
Journal of Physical and Chemical Reference Data, 41(4), 043107-043107 (2012)
Nicholas A Isley et al.
Journal of the American Chemical Society, 135(47), 17707-17710 (2013-11-15)
New technology has been developed that enables Suzuki-Miyaura couplings involving widely utilized MIDA boronates to be run in water as the only medium, mainly at room temperature. The protocol is such that no organic solvent is involved at any stage;
Jeffrey A Crank et al.
Journal of the American Society for Mass Spectrometry, 20(10), 1790-1800 (2009-08-12)
Second generation ionic liquid matrices are developed, examined, and tested. They have shown a wide mass detection range (<1000 Da to >270,000 Da) for proteins and peptides with greater S/N ratios than solid matrices. These ionic liquid matrices also exhibit
Abhinaba Gupta et al.
ACS applied materials & interfaces, 5(3), 924-933 (2013-01-04)
This article describes the separation of mixtures of fatty acid salts using a new organic solvent nanofiltration membrane based on polydicyclopentadiene (PDCPD). Mixtures of free fatty acids could not be separated by the membranes because they permeated at similar rates.

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