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346578

Sigma-Aldrich

5-Phenyl-1,3-cyclohexanedione

96%

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모든 사진(1)

About This Item

Linear Formula:
C6H5C6H7(=O)2
CAS Number:
493-72-1
Molecular Weight:
188.22
MDL number:
MFCD00051846
UNSPSC 코드:
12352100
PubChem Substance ID:
24861418
NACRES:
NA.22

분석

96%

mp

188 °C (lit.)

SMILES string

O=C1CC(CC(=O)C1)c2ccccc2

InChI

1S/C12H12O2/c13-11-6-10(7-12(14)8-11)9-4-2-1-3-5-9/h1-5,10H,6-8H2

InChI key

UPPYKNLSSLIIAZ-UHFFFAOYSA-N

일반 설명

5-Phenyl-1,3-cyclohexanedione is a 1,3-diketone. Reaction of 5-phenyl-1,3-cyclohexanedione with N-substituted isatins in pyrindine has been investigated.

애플리케이션

5-Phenyl-1,3-cyclohexanedione may be used:
  • in the synthesis of hexahydrobenzo[a]phenanthridin-4-one derivatives via condensation with N-arylmethylene-2-naphthylamines
  • in the preparation of benzophenanthridine derivatives
  • in the preparation of iodonium betaine
  • in the synthesis of various 2H-pyrans by iodine-catalyzed reactions

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)

시험 성적서(COA)

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1,3-Indandione 97%

Sigma-Aldrich

I2002

1,3-Indandione

Phenyl vinyl sulfone 99%

Sigma-Aldrich

241717

Phenyl vinyl sulfone

Reactions of bisazomethines of the naphtalene series with 1, 3-diketones.
Kozlov SN, et al.
Russ. J. Gen. Chem., 73(9), 1424-1440 (2009)
Chunhui Dai et al.
Beilstein journal of organic chemistry, 8, 986-993 (2012-09-29)
A mild and practical synthesis of spirooxindole [1,3]oxazino derivatives from N-substituted isatins and 1,3-dicarbonyl compounds with pyridine derivatives is reported. The reactions provided good to excellent yields. Further exploration of the molecular diversity of these compounds is demonstrated through Diels-Alder
Efforts toward the synthesis of liphatic iodonium salts.
Dence JB and Roberts JD.
The Journal of Organic Chemistry, 33(3), 1251-1253 (1968)
Synthesis of Benzo [a] phenanthridine Derivatives by Condensation of N-Arylmethylene-2-naphthylamines with 5-Phenyl-and 5-(p-Methoxyphenyl)-1, 3-cyclohexanediones.
Kozlov NG, et al.
Russ. J. Gen. Chem., 72(8), 1238-1242 (2002)
Iodine-Catalyzed One-Pot Synthesis of 2H-Pyrans by Domino Knoevenagel/6p-Electrocylization.
Jung EJ, et al.
Bull. Korean Chem. Soc., 30, 2833-2836 (2009)

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