332364

Allyltriphenylstannane

97%

• 동의어(들): 2-Propenyl-triphenylstannane, Allyltriphenyltin
• Linear Formula: CH₂=CHCH₂Sn(C₆H₅)₃
• CAS Number: 76-63-1
• Molecular Weight: 391.09
• Beilstein: 3612762
• EC Number: 200-975-4
• MDL number: MFCD00048162
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24859890
• NACRES: NA.22

속성

• 분석: 97%
• 양식: solid
• mp: 71-74 °C (lit.)
• SMILES string: C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;
• InChI key: NDUYAGLANMHJHF-UHFFFAOYSA-N

설명

일반 설명

Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.[1]

애플리케이션

Allyltriphenylstannane can be used:

• As a reagent in the C-H phenylation of azoles catalyzed by palladium.[2]
• As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)₃.[3]
• As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.[4]

안전성 정보

• 픽토그램: GHS06,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H301 + H311 + H331,H410
• 예방조치 성명서: P261 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type N95 (US)