319716

(1R)-(+)-Camphorsulfonylimine

99%

• 동의어(들): (3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide, (7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0^1,5]dec-4-ene 3,3-dioxide
• 실험식(Hill 표기법): C₁₀H₁₅NO₂S
• CAS Number: 107869-45-4
• Molecular Weight: 213.30
• Beilstein: 85297
• MDL number: MFCD00064576
• UNSPSC 코드: 12352005
• PubChem Substance ID: 24859182

속성

• 분석: 99%
• 광학 활성: [α]20/D +34°, c = 1 in chloroform
• mp: 229-230 °C (lit.)
• SMILES string: CC1(C)C2CC[C@@]13CS(=O)(=O)N=C3C2
• InChI: 1S/C10H15NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7H,3-6H2,1-2H3/t7?,10-/m0/s1
• InChI key: ZAHOEBNYVSWBBW-MHPPCMCBSA-N

설명

애플리케이션

(R) and (S) forms are precursors to chiral (camphorsulfonyl)oxaziridines employed in the asymmetric hydroxylation of ester and amide enolates.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves