콘텐츠로 건너뛰기
Merck
모든 사진(2)

문서

309281

Sigma-Aldrich

Iron(III) perchlorate hydrate

crystalline

동의어(들):

Perchloric acid iron(III) salt hydrate

로그인조직 및 계약 가격 보기


About This Item

Linear Formula:
Fe(ClO4)3 · xH2O
CAS Number:
Molecular Weight:
354.20 (anhydrous basis)
EC Number:
MDL number:
UNSPSC 코드:
12352000
PubChem Substance ID:
NACRES:
NA.22

형태

crystalline

반응 적합성

reagent type: oxidant

불순물

<0.10% chloride

색상

yellow

SMILES string

[Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3

InChI key

PFPIMAZLJXJVAN-UHFFFAOYSA-K

유사한 제품을 찾으십니까? 방문 제품 비교 안내

관련 카테고리

애플리케이션

Catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization
Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:
  • Fullerene-fused lactones
  • α-Carbonyl furans via one-pot cyclization
  • Fullerodioxolanes via heterocyclization
  • Fulleroxazolidines
  • Dialylated indoles via double alkylation
  • Aryl esters via oxidative esterification

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

픽토그램

Flame over circleExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

표적 기관

Respiratory system

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

A facile access to [60] fullerene-fused 1, 3-dioxolanes: Reaction of [60] fullerene with aldehydes/ketones promoted by ferric perchlorate.
Li FB, et al
Organic Letters, 12(14), 3258-3261 (2010)
Ferric Perchlorate Promoted Reaction of [60] Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines.
Liu TX, et al.
The Journal of Organic Chemistry, 80(24), 11986-11992 (2015)
Iron salt-catalyzed cascade type one-pot double alkylation of indole with vinyl ketones.
Kobayashi JK, et al.
Tetrahedron, 66(22), 3917-3922 (2010)
Diverse redox chemistry of photo/ferrioxalate system.
Wang Z, et al.
Royal Society of Chemistry Advances, 4(84), 44654-44658 (2014)
Structural characterization of a tris-salicylate coordination for iron (III) with the tripodal ligand O-TRENSOX.
Serratrice G, et al.
Inorganic Chemistry, 38(5), 840-841 (1999)

자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

고객지원팀으로 연락바랍니다.