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Merck
모든 사진(2)

문서

283207

Sigma-Aldrich

Magnesium bis(monoperoxyphthalate) hexahydrate

greener alternative

80%, technical grade

동의어(들):

MMPP

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About This Item

Linear Formula:
(HO2CC6H4CO3)2Mg·6H2O
Molecular Weight:
494.64
EC Number:
MDL number:
UNSPSC 코드:
12352002
PubChem Substance ID:
NACRES:
NA.22

Grade

technical grade

분석

80%

반응 적합성

reagent type: oxidant

환경친화적 대안 제품 특성

Designing Safer Chemicals
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

93 °C (dec.) (lit.)

환경친화적 대안 카테고리

SMILES string

O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO

InChI

1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2

InChI key

WWOYCMCZTZTIGU-UHFFFAOYSA-L

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals". For more information see the below articles.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.

애플리케이션

A safer, greener oxidizing reagent that is a suitable replacement for peroxycarboxylic acids and is capable of effecting many types of oxidation reactions.

Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid
Reagent for:
  • Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
  • Oxidation rections under mild conditions
  • Epoxidation of unsaturated steroids
  • Synthesis of ring-B oxygenated steroids as anticancer agents

픽토그램

FlameCorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


시험 성적서(COA)

제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Heaney, H.; Newbold, A. J.
Tetrahedron Letters, 42, 6607-6607 (2001)
Wasserman, H. H. et al
Tetrahedron Letters, 43, 3351-3351 (2002)
Ming-Yi Chen et al.
The Journal of organic chemistry, 69(8), 2884-2887 (2004-04-13)
A protocol that uses moist magnesium monoperoxyphthalate (MMPP) as an oxidant under microwave irradiation rapidly yields a variety of glycosyl sulfoxides from corresponding sulfides in high yields with high selectivity.
Broughan, P. et al
Synthesis, 1015-1015 (1987)
Chan-Woo Park et al.
Journal of microbiology and biotechnology, 27(7), 1359-1366 (2017-05-18)
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문서

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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