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Merck
모든 사진(3)

문서

221171

Sigma-Aldrich

Pinacol

98%

동의어(들):

2,3-Dimethyl-2,3-butanediol, Tetramethylethylene glycol

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모든 사진(3)

About This Item

Linear Formula:
HOC(CH3)2C(CH3)2OH
CAS Number:
76-09-5
Molecular Weight:
118.17
Beilstein:
1340501
EC Number:
200-933-5
MDL number:
MFCD00004462
UNSPSC 코드:
12352100
PubChem Substance ID:
24853219
NACRES:
NA.22

Quality Level

200

분석

98%

형태

solid

bp

171-172 °C/739 mmHg (lit.)

mp

40-43 °C (lit.)

solubility

alcohol: freely soluble
diethyl ether: freely soluble
hot water: freely soluble

SMILES string

CC(C)(O)C(C)(C)O

InChI

1S/C6H14O2/c1-5(2,7)6(3,4)8/h7-8H,1-4H3

InChI key

IVDFJHOHABJVEH-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

The pinacol coupling reaction with the inorganic electride [Ca2N](+)·e(−) as an electron donor in organic solvents was studied.

애플리케이션

Pinacol is a 1,2-diol that can be used:
  • As a ligand to prepare uranyl complexes by reacting with uranyl nitrate and acetate hydrates.
  • To prepare pinacolone and 2,3-dimethyl-1,3-butadiene by typical pinacol rearrangement reaction.
  • As a reactant to synthesize 4-(4,4,5,5-tetramethyl-1,3,2-bioxaborolan-2-yl)benzoic acid, which is used to prepare derivatives of 4-acetoxy-3-phenylbenzaldehyde.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point (°F)

170.6 °F - closed cup

Flash Point (°C)

77 °C - closed cup

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves

시험 성적서(COA)

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문서 라이브러리 방문

Uranyl complexes with 1, 2-diols and tetrahydrofurfuryl alcohols
Villiers C, et al.
Polyhedron, 46(1), 133-138 (2012)
Ye Ji Kim et al.
Chemical communications (Cambridge, England), 50(37), 4791-4794 (2014-04-02)
The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N](+)·e(-) as an electron donor in organic solvents. The bond cleavages of the [Ca2N](+) layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying
Fe-substituted molecular sieves as catalysts in liquid phase pinacol rearrangement
Hsien M, et al.
J. Mol. Catal. A: Chem., 181(1-2), 189-200 (2002)
New extraction procedure for protonated polyoxometalates prepared in aqueous-organic solution and characterisation of their catalytic ability
Ueda T, et al.
Applied Catalysis A: General, 485(1-2), 181-187 (2014)
Synthesis of polymer-bound 4-acetoxy-3-phenylbenzaldehyde derivatives: applications in solid-phase organic synthesis
Kumar A, et al.
The Journal of Organic Chemistry, 71(20), 7915-7918 (2006)
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