추천 제품
분석
96%
mp
94-97 °C (lit.)
solubility
benzene: soluble
diethyl ether: soluble
ethylene chloride: soluble
glacial acetic acid: soluble
methylene chloride: soluble
trichloroethylene: soluble
xylene: soluble
저장 온도
2-8°C
SMILES string
[O-][N+](=O)c1ccc(SCl)c(c1)[N+]([O-])=O
InChI
1S/C6H3ClN2O4S/c7-14-6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H
InChI key
GPXDNWQSQHFKRB-UHFFFAOYSA-N
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일반 설명
2,4-Dinitrobenzenesulfenyl chloride undergoes addition reactions with transannularly substituted cycloalkenes and norbornenes. 2,4-Dinitrobenzenesulfenyl chloride can convert allylic alcohols to dienes by 1,4-elimination.
애플리케이션
2,4-Dinitrobenzenesulfenyl chloride was used in preparation of chlorine and bromine biphenyls.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Synthesis of chlorinated and brominated biphenyl oxides.
Reich LL and Reich HJ.
The Journal of Organic Chemistry, 46(18), 3721-3727 (1981)
G K Kumar et al.
Biochemistry, 27(16), 5978-5983 (1988-08-09)
Transcarboxylase (TC) from Propionibacterium shermanii consists of a central hexameric 12S subunit to which 6 outer dimeric 5S subunits are attached through 12 biotinyl 1.3S subunits. The enzyme catalyzes the transfer of a carboxyl group from methylmalonyl-CoA to pyruvate, forming
Studies on the Effect of Remote Substituents on Reactivity: The Rates of Addition of 2, 4-Dinitrobenzenesulfenyl Chloride to Cyclohexenes and Norbornenes (I) 1a.
Kwart H and Miller LJ.
Journal of the American Chemical Society, 83(22), 4552-4559 (1961)
M J De Wolf et al.
The Journal of biological chemistry, 256(11), 5481-5488 (1981-06-10)
The tryptophan residues on cholera toxin and its A and B protomers have been modified by reaction with 2-nitrophenylsulfenyl chloride and 2,4-dinitrophenylsulfenyl chloride. Modification of the tryptophan residues of cholera toxin results in complete loss of toxicity measured in a
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