02615

(Ethoxycarbonylmethyl)triphenylphosphonium chloride

technical, ≥90% (AT)

• 동의어(들): (2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride
• Linear Formula: CH₃CH₂OCOCH₂P(Cl)(C₆H₅)₃
• CAS Number: 17577-28-5
• Molecular Weight: 384.84
• Beilstein: 3924139
• EC Number: 241-548-2
• MDL number: MFCD00011746
• UNSPSC 코드: 12352108
• PubChem Substance ID: 24845340
• NACRES: NA.22

속성

• grade: technical
• 분석: ≥90% (AT)
• 반응 적합성: reaction type: C-C Bond Formation
• mp: 120-123 °C (dec.); 120-123 °C (lit.)
• 작용기: ester; phosphine
• 저장 온도: 2-8°C
• SMILES string: [Cl-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
• InChI key: DJGHVEPNEJKZBF-UHFFFAOYSA-M

설명

애플리케이션

Reactant for:

• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
• Ring-opening reactions with Wittig reagents
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
• Preparation of phosphonium derivatives of coumarin

기타 정보

Starting material for preparing the Wittig-reagent

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves