277371

1-(Trimethylsilyl)pyrrolidine

97%

• Empirical Formula (Hill Notation): C₇H₁₇NSi
• CAS Number: 15097-49-1
• Molecular Weight: 143.30
• Beilstein: 1304636
• EC Number: 239-149-3
• MDL number: MFCD00003164
• UNSPSC Code: 12352100
• PubChem Substance ID: 24856758
• NACRES: NA.22

Properties

• Assay: 97%
• form: liquid
• refractive index: n20/D 1.433 (lit.)
• bp: 139-140 °C (lit.)
• density: 0.821 g/mL at 25 °C (lit.)
• SMILES string: C[Si](C)(C)N1CCCC1
• InChI: 1S/C7H17NSi/c1-9(2,3)8-6-4-5-7-8/h4-7H2,1-3H3
• InChI key: NQLVIKZJXFGUET-UHFFFAOYSA-N

Description

Application

1-(Trimethylsilyl)pyrrolidine (N-trimethylsilyl pyrrolidine) has been used in:

• ring opening reaction of L-serine β-lactone to yield corresponding 5-amino-L-alanine derivatives
• the preparation of iminium triflate salts

Safety Information

• Pictograms: GHS02,GHS05
• Signal Word: Danger
• Hazard Statements: H225,H314
• Precautionary Statements: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 39.2 °F - closed cup
• Flash Point(C): 4 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves