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516961

Sigma-Aldrich

Ammonium formate

≥99.995% trace metals basis

Synonym(s):

Formic acid ammonium salt

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About This Item

Linear Formula:
HCO2NH4
CAS Number:
540-69-2
Molecular Weight:
63.06
Beilstein:
3625095
EC Number:
208-753-9
MDL number:
MFCD00013103
UNSPSC Code:
12352107
eCl@ss:
39021903
PubChem Substance ID:
24873910
NACRES:
NA.23

Quality Level

200

Assay

≥99.995% trace metals basis

form

crystalline

impurities

≤50.0 ppm Trace Metal Analysis

mp

119-121 °C (lit.)

density

1.26 g/mL at 25 °C (lit.)

SMILES string

N.OC=O

InChI

1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3

InChI key

VZTDIZULWFCMLS-UHFFFAOYSA-N

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General description

Ammoniumformate is a derivative of formic acid widely used as a hydrogen transfer reagentand formylating agent. It is also used in the preparation and storage of formicacid.

Application

Ammonium formate can be used as:
  • Hydrogen source in reduction of aromatic nitro compounds to corresponding amino derivatives in presence of Cu nanoparticles as catalyst.
  • Formylating agent for synthesis of N-formyl amino acid esters.
  • An OH radical scavenger in the preparation of nanocrystalline uranium and/or thorium oxides.

Features and Benefits

  • Inexpensive and readily available
  • Stable and non-toxic
  • Can be used in conjugation with Pd/C andRaney-Nickel catalyst.
  • Can be easily separated from the reaction mixture

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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