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363359

Sigma-Aldrich

2-Butene, mixture of cis and trans

≥99%

Synonym(s):

β-Butylene, Pseudobutylene

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About This Item

Linear Formula:
CH3CH=CHCH3
CAS Number:
107-01-7
Molecular Weight:
56.11
Beilstein:
1718755
EC Number:
203-452-9
MDL number:
MFCD00064458
UNSPSC Code:
12352100
PubChem Substance ID:
24862193
NACRES:
NA.22

vapor pressure

1.9 mmHg ( 0 °C)

Quality Level

100

Assay

≥99%

expl. lim.

9.3 %

bp

1 °C (lit.)

mp

−140 °C (lit.)

SMILES string

C\C=C\C

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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General description

2-Butene is an alkene. All-silica zeolite RUB-41, containing 8- and 10-membered rings, is reported to be capable of separating trans-2-butene and cis-2-butene from 1-butene. Asymmetric gydrozirconation of cis- and trans-2-butene is reported. Stereospecific addition of methylene to trans-2-butene is reported to afford trans-1,2dimethylcyclopropane while similar addition to cis-2-butene affords cis-1,2dimethylcyclopropane.

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Pictograms

FlameGas cylinder
GHS02,GHS04

Signal Word

Danger

Hazard Statements

H220,H280

Precautionary Statements

P410 + P403

Hazard Classifications

Flam. Gas 1 - Press. Gas Liquefied gas

Storage Class Code

2A - Gases

WGK

nwg

Flash Point(F)

-29.2 °F - closed cup

Flash Point(C)

-34 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Yonghui Zhang et al.
Journal of the American Chemical Society, 125(29), 8746-8747 (2003-07-17)
Hydrozirconation of cis-2-butene with Cp*ZrHCl[N(t-Bu)C(Me)N(Et)], generated in situ through hydrogenolysis of Cp*ZrCl(SiMe2Ph)[N(t-Bu)C(Me)N(Et)] (5), proceeds in high yield to produce a 1:2 mixture of the kinetically stable, diastereomeric sec-butyl complexes, 3a and 3b. Hydrozirconation of trans-2-butene under identical conditions provides a
Methylene, CH2. Stereospecific Reaction with cis-and trans-2-Butene.
Woodworth RC and Skell PS.
Journal of the American Chemical Society, 81(13), 3383-3386 (1959)
Philip T M Carlsson et al.
Physical chemistry chemical physics : PCCP, 14(45), 15637-15640 (2012-10-24)
Recent studies have suggested that the reaction of stabilised Criegee Intermediates (CIs) with sulfur dioxide (SO(2)), leading to the formation of a carbonyl compound and sulfur trioxide, is a relevant atmospheric source of sulfuric acid. Here, the significance of this
Nadiya Bakhiya et al.
Archives of toxicology, 84(7), 563-578 (2010-03-20)
Furan is formed during commercial or domestic thermal treatment of food. The initial surveys of furan concentrations in heat-treated foods, published by European and US authorities, revealed the presence of relatively high furan levels in coffee, sauces, and soups. Importantly
Franz Worek et al.
Archives of toxicology, 86(9), 1379-1386 (2012-03-23)
The reactivation of organophosphorus compound (OP)-inhibited acetylcholinesterase (AChE) by oximes is inadequate in case of different OP nerve agents. This fact led to the synthesis of numerous novel oximes by different research groups in order to identify more effective reactivators.
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