CRM55869

Clofentezine

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): 3,6-Bis(2-chlorophenyl)-1,2,4,5-tetrazine, Clofentezine
• Empirical Formula (Hill Notation): C₁₄H₈Cl₂N₄
• CAS Number: 74115-24-5
• Molecular Weight: 303.15
• Beilstein: 7137128
• MDL number: MFCD00143998
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• mp: 182-185 °C (lit.)
• format: neat
• storage temp.: 2-8°C
• SMILES string: Clc1ccccc1-c2nnc(nn2)-c3ccccc3Cl
• InChI: 1S/C14H8Cl2N4/c15-11-7-3-1-5-9(11)13-17-19-14(20-18-13)10-6-2-4-8-12(10)16/h1-8H
• InChI key: UXADOQPNKNTIHB-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Clofentezine is a tetrazine group containing insecticide used against phytophagous mites on citrus fruits, vines, cotton crops, and ornamentals.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, clofentezine is approved for plant protection use in the European Union (EU). A maximum residue limit (MRL) of 0.5 mg/kg and 0.05 mg/kg is applicable for the presence of clofentezine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2015/846. Clofentezine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.

• The clofentezine CRM may also find following uses:
• Development and validation of a high-performance liquid chromatography-diode-array detection (HPLC-DAD) method following a dispersive solid phase extraction using zirconia-coated silica particles for the analysis of 21 pesticide residues in oil samples
• Development of a sample preparation method based on magnetic mixed hemimicelles dispersive solid-phase extraction (MMHDSPE) to separate three acaricides from three fruit juice samples
• Multi-residue determination of 60 pesticide residues in hen eggs using QuEChERS extraction followed by an LC-MS/MS or GC-MS/MS quantification
• Simultaneous analysis of 302 pesticides and contaminants in ten catfish samples by low-pressure GC-MS/MS and UHPLC-MS/MS
• GC-MS/MS and LC-MS/MS based determination of 314 pesticide residues in raisin samples for their risk exposure assessment
• Simultaneous analysis of 300 pesticide residues in human hair samples by GC-MS/MS and LC-MS/MS

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS09
• Signal Word: Warning
• Hazard Statements: H410
• Precautionary Statements: P273 - P391 - P501
• Hazard Classifications: Aquatic Chronic 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable