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Key Documents

62470

Sigma-Aldrich

Lithium carbonate

puriss. p.a., ACS reagent, reagent (for microscopy), ≥99.0% (T)

Synonym(s):

Carbolithium, Carbonic acid lithium salt

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About This Item

Linear Formula:
Li2CO3
CAS Number:
Molecular Weight:
73.89
Beilstein:
3999191
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent
reagent (for microscopy)
puriss. p.a.

Assay

≥99.0% (T)

form

powder

pH

9-11 (1 g/L)

mp

618 °C (lit.)

anion traces

chloride (Cl-): ≤20 mg/kg
nitrate (NO3-): ≤5 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Mg: ≤10 mg/kg
Mn: ≤5 mg/kg
NH4+: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤0.002% (by ICP-OES)

SMILES string

[Li+].[Li+].[O-]C([O-])=O

InChI

1S/CH2O3.2Li/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

XGZVUEUWXADBQD-UHFFFAOYSA-L

Gene Information

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General description

Lithium carbonate (Li2CO3), a lithium salt, is a white monoclinic crystalline solid. Its industrial preparation has been described. In laboratory, it can be synthesized by reacting carbon dioxide gas with a lithium hydroxide solution.

Application

Lithium carbonate (Li2CO3) may be used in the following studies:
  • As a precursor in the preparation of LiFe1-yVyPO4 solid solutions.
  • As a starting reagent for the synthesis of various lithium salts (lithium chloride and lithium bromide).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Vanadium modified LiFePO4 cathode for Li-ion batteries.
Hong J, et al
Electrochemical and Solid-State Letters, 12(2), A33-A38 (2009)
K E Morrison et al.
The Lancet. Neurology, 12(4), 339-345 (2013-03-05)
Lithium has neuroprotective effects in cell and animal models of amyotrophic lateral sclerosis (ALS), and a small pilot study in patients with ALS showed a significant effect of lithium on survival. We aimed to assess whether lithium improves survival in
Hart WA, et al.
The Chemistry of Lithium, Sodium, Potassium, Rubidium, Cesium and Francium, 355-355 (1973)
N Alessi et al.
Journal of the American Academy of Child and Adolescent Psychiatry, 33(3), 291-304 (1994-03-01)
The use of lithium to treat child and adolescent psychiatric disorders is becoming more common. Since the publication of the report of The Committee on Biological Aspects of Child Psychiatry of the American Academy of Child Psychiatry in 1978, a
Tom Bschor et al.
Journal of clinical psychopharmacology, 33(1), 38-44 (2013-01-02)
Studies of the 1970s and 1980s showed lithium monotherapy to be an effective treatment of acute unipolar major depressive disorder (MDD) and hence as a potential alternative to monoaminergic antidepressants.The objective was to conduct the first comparison of a lithium

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