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346144

Sigma-Aldrich

Diethyl ether

≥98%, reagent grade, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

Synonym(s):

Et2O, Ethoxyethane, Ether, Ethyl ether

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About This Item

Linear Formula:
(CH3CH2)2O
CAS Number:
Molecular Weight:
74.12
Beilstein:
1696894
EC Number:
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.07

product name

Diethyl ether, reagent grade, ≥98%, contains ≤2% ethanol and ≤10ppm BHT as inhibitor

grade

reagent grade

vapor density

2.6 (vs air)

vapor pressure

28.5 psi ( 55 °C)
8.38 psi ( 20 °C)

Assay

≥98%

form

liquid

autoignition temp.

320 °F
356 °F

contains

≤2% ethanol and ≤10ppm BHT as inhibitor

expl. lim.

36.5 %

impurities

≤0.5% (water)

refractive index

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

density

0.706 g/mL at 25 °C (lit.)

SMILES string

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChI key

RTZKZFJDLAIYFH-UHFFFAOYSA-N

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General description

Diethylether, also known as ethyl ether or ether, is frequently used as a laboratory solvent. It is highly volatile, non-flammable, has limited solubility in water, and has high solubility in oil. Ethers are favored solvents for oils, fats, waxes, perfumes, dyes, resins, gums, and hydrocarbons. Additionally, it can be used as a fuel and to synthesize other chemical compounds. It is also employed as a solvent for Grignard synthesis.

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup


Certificates of Analysis (COA)

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Oxidation mechanism of diethyl ether: a complex process for a simple molecule
Di Tommaso S, et al.
Physical Chemistry Chemical Physics, 13(32), 14636-14645 (2011)
The grignard reagents
Seyferth D
Organometallics, 28(6), 1598-1605 (2009)
A review on the advancement of ether synthesis from organic solvent to water
Mandal S, et al.
Royal Society of Chemistry Advances, 6(73), 69605-69614 (2016)
The potency of hydrothermally prepared sulfated silica (SO4/SiO2) as a heterogeneous acid catalyst for ethanol dehydration into diethyl ether
Pratika RA, et al.
Chemosphere, 341, 139822-139822 (2023)
Tatsuya Yoshino et al.
Organic letters, 14(16), 4290-4292 (2012-08-09)
A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C-O bond formation from differently substituted diphenols.

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