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Permethrin

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C21H20Cl2O3
CAS Number:
52645-53-1
Molecular Weight:
391.29
Beilstein:
5765325
EC Number:
258-067-9
MDL number:
MFCD00041809
UNSPSC Code:
41116107
PubChem Substance ID:
329756835
NACRES:
NA.24

grade

analytical standard

Quality Level

100

description

mixture of cis and trans isomers

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC1(C)C(\C=C(/Cl)Cl)C1C(=O)OCc2cccc(Oc3ccccc3)c2

InChI

1S/C21H20Cl2O3/c1-21(2)17(12-18(22)23)19(21)20(24)25-13-14-7-6-10-16(11-14)26-15-8-4-3-5-9-15/h3-12,17,19H,13H2,1-2H3

InChI key

RLLPVAHGXHCWKJ-UHFFFAOYSA-N

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General description

Permethrin belongs to the pyrethroid class of insecticides.

Application

Permethrin may be used as an analytical reference standard for the determination of permethrin in:
  • Virgin olive oil samples by liquid-liquid extraction (LLE) or low-temperature precipitation followed by Sep-Pak alumina-N column clean-up and analysis using gas chromatography equipped with electron capture detector (GC-ECD).
  • Whole blood samples by electron ionization GC coupled to mass spectrometry (MS) operating in selected ion monitoring (SIM) mode.
  • Tomato sample extracts by high performance liquid chromatography (HPLC) with post-column photoderivatization and acetonitrile chemiluminescence based detection.
  • Water samples by ultrasound-assisted emulsification-extraction (UAEE) and GC-negative ion chemical ionization (NCI) MS.
  • Apple juice samples by matrix solid-phase dispersion (MSPD) and GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Analysis Note

appearance: Yellow to brownish liquid, might be crystallized at room temperature

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302 + H332 - H317 - H410

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK6169
BCCB2182
BCBV7205
BCBT9053
SZBD142XV

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Determination of nine pyrethroid insecticides by high-performance liquid chromatography with post-column photoderivatization and detection based on acetonitrile chemiluminescence.
Galera MM, et al.
Journal of Chromatography A, 1113(1-2), 191-197 (2006)
A rapid and sensitive analytical method for the determination of 14 pyrethroids in water samples.
Feo ML, et al.
Journal of Chromatography A, 1217(15), 2248-2253 (2010)
Nigel B Perry et al.
Journal of natural products, 71(2), 258-261 (2008-02-01)
Clavigerin A ( 1) was isolated from the New Zealand liverwort Lepidolaena clavigera and shown to be a polyoxygenated bergamotane sesquiterpene with an unusual ring system. L. clavigera shows infraspecific variation, since 1 was the only clavigerin detected in a
Klaus E Appel et al.
International journal of hygiene and environmental health, 211(1-2), 88-104 (2008-01-29)
In an age when vector-borne diseases are emerging worldwide, personal protective measures are essential for shielding soldiers and other exposed persons from arthropod attack. The development of permethrin-impregnated clothing has been one recent advance in protecting persons at-risk. However, to
Determination of 266 pesticide residues in apple juice by matrix solid-phase dispersion and gas chromatography-mass selective detection
Chu XG, et al.
Journal of Chromatography A, 1063(1-2), 201-210 (2005)
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