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33658

Supelco

Picoxystrobin

PESTANAL®, analytical standard

Synonym(s):

Methyl (E)-α-methoxymethylene-2-(3-trifluoromethyl-2-pyridyloxymethyl)phenylacetate

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About This Item

Empirical Formula (Hill Notation):
C18H16F3NO4
CAS Number:
117428-22-5
Molecular Weight:
367.32
MDL number:
MFCD04112618
UNSPSC Code:
41116107
PubChem Substance ID:
329754607
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CO\C=C(/C(=O)OC)c1ccccc1COc2cccc(n2)C(F)(F)F

InChI

1S/C18H16F3NO4/c1-24-11-14(17(23)25-2)13-7-4-3-6-12(13)10-26-16-9-5-8-15(22-16)18(19,20)21/h3-9,11H,10H2,1-2H3/b14-11-

InChI key

IBSNKSODLGJUMQ-KAMYIIQDSA-N

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General description

Picoxystrobin is classified under the strobulins family of fungicides that exhibit broad range activity against plant pathogenspathogenic fungi.

Application

Picoxystrobin may be used as a reference standard for the determination of picoxystrobin in:
  • Honeybees using acetonitrile-based extraction followed by dispersive solid-phase extraction (d-SPE) cleanup and gas chromatography−tandem quadrupole mass spectrometry (GC−MS/MS).
  • Foodstuffs by liquid chromatography (LC) combined with MS/MS, atmospheric pressure chemical ionization (APCI) and electrospray ionization (ESI).
  • Paddy field water by direct injection using LC coupled with quadrupole-linear ion trap (QqLIT)-MS.
  • Maize by acetonitrile-based extraction with dispersive liquid−liquid microextraction (DLLME) followed by GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H332,H410

Precautionary Statements

P273 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ8694
BCCF8512
BCBX0885
BCBW4007
SZBD116XV

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The ECHO technique-the more effective way of data evaluation in liquid chromatography-tandem mass spectrometry analysis
Alder L, et al.
Journal of Chromatography A, 1058(1-2), 67-79 (2004)
Yangyang Gao et al.
Ecotoxicology and environmental safety, 182, 109445-109445 (2019-07-23)
In this study, a new, high-efficiency and sensitive method was determined to simultaneous analyze the residue of pyraclostrobin, picoxystrobin and its metabolite BF-500-3 in pepper fruit using modified QuEChERS pretreatment combined with ultra performance liquid chromatography-tandem mass spectrometry. The clean-up
Stir bar sorptive extraction coupled to liquid chromatography for the analysis of strobilurin fungicides in fruit samples
Campillo N, et al.
Journal of Chromatography A, 1217(27), 4529-4534 (2010)
Marianne Stenrød et al.
PloS one, 8(6), e66989-e66989 (2013-07-03)
There is widespread use of chemical amendments to meet the demands for increased productivity in agriculture. Potentially toxic compounds, single or in mixtures, are added to the soil medium on a regular basis, while the ecotoxicological risk assessment procedures mainly
Xinzhong Zhang et al.
Journal of the science of food and agriculture, 101(1), 194-204 (2020-07-06)
Picoxystrobin is a new osmotic and systemic broad-spectrum methoxyacrylate fungicide with a good control effect on tea anthracnose, so it has been proposed to spray picoxystrobin before the occurrence and onset of tea anthracnose during tea bud growth in order
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