Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

B58407

Sigma-Aldrich

4-Bromobenzonitrile

99%

Synonym(s):

1-Bromo-4-benzonitrile, 1-Bromo-4-cyanobenzene, 1-Cyano-4-bromobenzene, 4-Bromocyanobenzene, 4-Bromophenyl cyanide, 4-Bromophenylcarbonitrile

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
BrC6H4CN
CAS Number:
623-00-7
Molecular Weight:
182.02
Beilstein:
2041518
EC Number:
210-764-9
MDL number:
MFCD00001811
UNSPSC Code:
12352100
PubChem Substance ID:
24891868
NACRES:
NA.22

Quality Level

200

Assay

99%

form

solid

bp

235-237 °C (lit.)

mp

110-115 °C (lit.)

SMILES string

Brc1ccc(cc1)C#N

InChI

1S/C7H4BrN/c8-7-3-1-6(5-9)2-4-7/h1-4H

InChI key

HQSCPPCMBMFJJN-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

4-Bromobenzonitrile has been used in the synthesis of 4-iodobenzonitrile via photo-induced aromatic Finkelstein iodination reaction. It can also be used as an aryl halide test compound in developing greener reaction conditions for Suzuki cross-coupling between aryl halides and phenyl boronic acid.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302 + H312,H319,H412

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Photo-induced iodination of aryl halides under very mild conditions.
Li L
Nature Protocols, 11(10), 1948-1948 (2016)
Magnetic nanoparticle?tethered Schiff base?palladium (II): Highly active and reusable heterogeneous catalyst for Suzuki?Miyaura cross?coupling and reduction of nitroarenes in aqueous medium at room temperature.
Manjunatha K
Applied Organometallic Chemistry (2018)
Takato Mitsudome et al.
Chemical science, 11(26), 6682-6689 (2020-09-22)
The study of metal phosphide catalysts for organic synthesis is rare. We present, for the first time, a well-defined nano-cobalt phosphide (nano-Co2P) that can serve as a new class of catalysts for the hydrogenation of nitriles to primary amines. While
A new air and moisture stable robust bio?polymer based palladium catalyst for highly efficient synthesis of biaryl compounds.
Baran T
Applied Organometallic Chemistry, 32(2) (2018)
Luca Quattrini et al.
Scientific reports, 9(1), 9943-9943 (2019-07-11)
Melanoma is the most serious form of skin cancer but its medication is still far from being safe and thoroughly effective. The search of novel therapeutic approaches represents therefore a health emergency to push through eagerly. In this study, we
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service