75991

Palladium on activated charcoal

moistened with water, 5% Pd basis (based on dry substance)

• Synonym(s): Pd/C
• Linear Formula: Pd
• MDL number: MFCD03457879
• UNSPSC Code: 12161600
• PubChem Substance ID: 57652601
• NACRES: NA.22

Properties

• form: paste
• quality: moistened with water
• contains: ~50% water as stabilizer
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• greener alternative product characteristics: Designing Safer Chemicals; Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• concentration: 5% Pd (based on dry substance)
• greener alternative category: , Aligned
• SMILES string: [Pd]
• InChI: 1S/Pd
• InChI key: KDLHZDBZIXYQEI-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Palladium on activated charcoal can be used as a heterogeneous catalyst:

• To synthesize methyl esters via oxidative esterification of primary alcohols.
• In the hydrogenation of phenol to cyclohexanone.
• For carbonylation of iodoanilines with amines and trimethyl orthoformate to prepare quinazolinones.
• In the hydrodehalogenation of aromatic halides to form arenes in aqueous media.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves