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697745

Sigma-Aldrich

Cobalt

Carbon coated magnetic, nanopowder, <50 nm particle size (TEM), ≥99%

Synonym(s):

Cobalt element, Cobalt-59

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About This Item

Empirical Formula (Hill Notation):
Co
CAS Number:
7440-48-4
Molecular Weight:
58.93
MDL number:
MFCD00010935
UNSPSC Code:
12352302
PubChem Substance ID:
329761949
NACRES:
NA.23

material

carbon

Assay

≥99%

form

nanopowder

composition

Carbon content, <8 wt. %

magnetization

>150 emu/g, Mass saturation

resistivity

6.24 μΩ-cm, 20°C

surface area

>15 m2/g

particle size

<50 nm (TEM)

bp

2900 °C (lit.)

density

8.9 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

[Co]

InChI

1S/Co

InChI key

GUTLYIVDDKVIGB-UHFFFAOYSA-N

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Application

Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Air- and thermally-stable magnetic carbon-coated cobalt nanoparticles (nanomagnets). Carbon shell consists of approximately three graphitic layers and can be chemically functionalized using e.g. diazotization reactions.

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chun Ghee Tan et al.
Chemical communications (Cambridge, England), (36), 4297-4299 (2008-09-20)
To develop magnetic nanomaterials applicable to organic synthesis, the Suzuki cross-coupling method was adapted to attach a range of functional groups to carbon-coated core-shell materials via commercially-available substituted arylboronic acids.
Luechinger, N.A.; Booth, N.; Heness, G.; Bandyopadhyay, S.; Grass, R.N.; Stark W.J.
Advanced Materials, 20, 3044-3044 (2008)
Covalently functionalized cobalt nanoparticles as a platform for magnetic separations in organic synthesis.
Robert N Grass et al.
Angewandte Chemie (International ed. in English), 46(26), 4909-4912 (2007-05-23)
Alexander Schätz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(27), 8262-8266 (2008-07-31)
TEMPO was grafted on graphene-coated nanobeads with a magnetic cobalt core by using a general applicable "click"-chemistry protocol. The new heterogeneous CoNP-TEMPO emerged as a highly active catalyst for the chemoselective oxidation of primary and secondary alcohols using bleach as
D W Su et al.
Journal of nanoscience and nanotechnology, 13(5), 3354-3359 (2013-07-19)
Highly ordered mesoporous Co3O4 nanostructures were prepared using SBA-15 silica as hard templates. The mesoporous structures were characterized by X-ray diffraction, high resolution transmission electron microscopy, and N2 adsorption/desorption isotherm analysis. The results demonstrated that the as-prepared mesoporous Co3O4 has
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