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Key Documents

471593

Sigma-Aldrich

N,N-Diethylhydroxylamine

≥98%

Synonym(s):

N-Hydroxydiethylamine, DEHA, Diethylhydroxylamine

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About This Item

Linear Formula:
(CH3CH2)2NOH
CAS Number:
Molecular Weight:
89.14
Beilstein:
1731349
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

3.07 (vs air)

vapor pressure

4 mmHg ( 0 °C)

Assay

≥98%

expl. lim.

10 %

refractive index

n20/D 1.420 (lit.)

bp

125-130 °C (lit.)

mp

−26-−25 °C (lit.)

density

0.867 g/mL at 25 °C (lit.)

SMILES string

CCN(O)CC

InChI

1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3

InChI key

FVCOIAYSJZGECG-UHFFFAOYSA-N

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General description

N,N-Diethylhydroxylamine (diethylhydroxylamine, DEHA, (C2H5)2NOH) is a N,N-dialkylhydroxylamine. Its interaction with the surface of clean silicon(100)-2x1 has been studied by various theoretical and spectroscopic methods. H2O2 along with superoxide and diethylnitroxide radicals have been reported to be formed during the photochemical oxidation of DEHA.

Application

N,N-Diethylhydroxylamine may be employed as a ligand in the preparation of unsymmetric mixed ligand oxadiazoline and/or imine platinum complexes. It may be used in the synthesis of organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc.

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

113.0 °F - closed cup

Flash Point(C)

45 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The first organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc, [Zn(MeZn)(4)(HNNMe(2))(2)(ONEt(2))(4)] and {Zn(EtZn)(4)[HNN(CH(2))(5)](2)(ONEt(2))(4)} were synthesized in one-pot synthesis protocols from dialkylzinc solutions, substituted hydrazines and N,N-diethylhydroxylamine; competing for the Zn atoms, the different binding properties of hydrazide and hydroxylamide ligands
C C Reddy et al.
Journal of toxicology and environmental health, 15(3-4), 467-475 (1985-01-01)
The effects of diethylhydroxylamine (DEHA), a potent free-radical scavenger, on lipid peroxidation of rat liver microsomes were investigated in vitro. DEHA strongly inhibited ascorbate-dependent nonenzymatic microsomal lipid peroxidation. DEHA also completely inhibited nonenzymatic lipid peroxidation of heat-denatured microsomes, indicating that
D Sharma et al.
Indian journal of experimental biology, 37(4), 355-358 (2000-01-21)
In vivo effects of diethylhydroxylamine (DEHA) on lipid peroxidation and lipofuscin formation in the nervous tissues of rat have been investigated. Rats were fed DEHA for 30, 60 and 90 days and lipid peroxidation levels and lipofuscin concentration measured in
J Heicklen
Annals of the New York Academy of Sciences, 502, 145-159 (1987-01-01)
Photochemical smog is caused by a free-radical chain mechanism which converts NO to NO2. The NO2 further reacts to produce ozone, nitric acid, and peracylnitrates. This chain mechanism can be inhibited by suitable free-radical scavengers. The chemistry and toxicology of

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