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About This Item
Linear Formula:
BrC6H4SO2Cl
CAS Number:
Molecular Weight:
255.52
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
solid
mp
49-52 °C (lit.)
SMILES string
ClS(=O)(=O)c1ccccc1Br
InChI
1S/C6H4BrClO2S/c7-5-3-1-2-4-6(5)11(8,9)10/h1-4H
InChI key
VFPWGZNNRSQPBT-UHFFFAOYSA-N
Related Categories
General description
2-Bromobenzenesulfonyl chloride can be synthesized from 2-aminobenzenesulfonic acid.
Application
2-Bromobenzenesulfonyl chloride may be used in the following:
- Preparation of 2-bromobenzenesulfonic acid phenyl ester.
- For the sufonylation during the synthesis of 2-bromobenzenesulfonamide.
- Synthesis of chiral 2-(p-toluenesulfinyl)benzenesulfonamide.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Synthesis of oxathiocine derivatives by palladium-catalyzed intramolecular Heck reaction.
Majumdar KC, et al.
Letters in Organic Chemistry, 6(6), 453-455 (2009)
Palladium-Catalysed Intramolecular Direct Arylation of 2-Bromobenzenesulfonic Acid Derivatives.
Bheeter C, et al.
Advanced Synthesis & Catalysis, 354(18), 3533-3538 (2012)
Studies on synthesis of 2-bromobenzenesulfonyl chloride.
CHENG X and JIANG Z-Q.
Tianjin Chemical Industry , 012-012 (2003)
Solid-phase synthesis of acyl biarylsulfonamides.
Xiong Y, et al.
Tetrahedron Letters, 42(48), 8423-8427 (2001)
Chiral sulfoxide ligands bearing nitrogen atoms as stereocontrollable coordinating elements in palladium-catalyzed asymmetric allylic alkylations.
Hiroi K, et al.
Tetrahedron Asymmetry, 9(21), 3797-3817 (1998)
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