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Key Documents

197637

Sigma-Aldrich

Imidazole sodium derivative

technical grade

Synonym(s):

Imidazolylsodium, Sodium imidazolide

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About This Item

Empirical Formula (Hill Notation):
C3H3N2Na
CAS Number:
Molecular Weight:
90.06
Beilstein:
3569312
EC Number:
MDL number:
UNSPSC Code:
12352005
eCl@ss:
39161001
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

mp

284 °C (dec.) (lit.)

SMILES string

[Na]n1ccnc1

InChI

1S/C3H3N2.Na/c1-2-5-3-4-1;/h1-3H;/q-1;+1

InChI key

ITAWMPSVROAMOE-UHFFFAOYSA-N

Application

Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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F G Earley et al.
The Biochemical journal, 224(2), 525-534 (1984-12-01)
A photoaffinity-labelling analogue of the respiratory inhibitor rotenone was synthesized from the naturally occurring rotenoid amorphigenin. The analogue inhibits NADH-ubiquinone oxidoreductase activity at concentrations comparable with those of rotenone. Photolysis of the radiolabelled analogue bound to isolated NADH-ubiquinone oxidoreductase resulted
Sun Un
Inorganic chemistry, 52(7), 3803-3813 (2013-03-21)
A common feature of a large majority of the manganese metalloenzymes, as well as many synthetic biomimetic complexes, is the bonding between the manganese ion and imidazoles. This interaction was studied by examining the nature and structure of manganese(II) imidazole
Eleonora Petryayeva et al.
Langmuir : the ACS journal of surfaces and colloids, 29(3), 977-987 (2013-01-10)
Methods have been developed for the solid-phase detection of nucleic acids using mixed films of quantum dots (QDs) and oligonucleotide probes in microtiter plates. Polystyrene microwells were functionalized with multidentate imidazole ligands to immobilize QDs. Oligonucleotide hybridization was transduced using
Chuanjiang Hu et al.
Inorganic chemistry, 52(6), 3170-3177 (2013-03-09)
The effects of the deprotonation of coordinated imidazole on the vibrational dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes
Yin Gao et al.
Bioorganic & medicinal chemistry, 21(5), 1305-1311 (2013-02-05)
Galactosyltransferases (GalTs) extend the glycan chains of mammalian glycoproteins by adding Gal to terminal GlcNAc residues, and thus build the scaffolds for biologically important glycan structures. We have shown that positively charged bivalent imidazolium salts in which the two imidazolium

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