197637
Imidazole sodium derivative
technical grade
Synonym(s):
Imidazolylsodium, Sodium imidazolide
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About This Item
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grade
technical grade
mp
284 °C (dec.) (lit.)
SMILES string
[Na]n1ccnc1
InChI
1S/C3H3N2.Na/c1-2-5-3-4-1;/h1-3H;/q-1;+1
InChI key
ITAWMPSVROAMOE-UHFFFAOYSA-N
Application
Imidazole sodium derivative (Imidazolylsodium) was used in the synthesis of arylazidoamorphigenin.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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The Biochemical journal, 224(2), 525-534 (1984-12-01)
A photoaffinity-labelling analogue of the respiratory inhibitor rotenone was synthesized from the naturally occurring rotenoid amorphigenin. The analogue inhibits NADH-ubiquinone oxidoreductase activity at concentrations comparable with those of rotenone. Photolysis of the radiolabelled analogue bound to isolated NADH-ubiquinone oxidoreductase resulted
Inorganic chemistry, 52(7), 3803-3813 (2013-03-21)
A common feature of a large majority of the manganese metalloenzymes, as well as many synthetic biomimetic complexes, is the bonding between the manganese ion and imidazoles. This interaction was studied by examining the nature and structure of manganese(II) imidazole
Langmuir : the ACS journal of surfaces and colloids, 29(3), 977-987 (2013-01-10)
Methods have been developed for the solid-phase detection of nucleic acids using mixed films of quantum dots (QDs) and oligonucleotide probes in microtiter plates. Polystyrene microwells were functionalized with multidentate imidazole ligands to immobilize QDs. Oligonucleotide hybridization was transduced using
Inorganic chemistry, 52(6), 3170-3177 (2013-03-09)
The effects of the deprotonation of coordinated imidazole on the vibrational dynamics of five-coordinate high-spin iron(II) porphyrinates have been investigated using nuclear resonance vibrational spectroscopy. Two complexes have been studied in detail with both powder and oriented single-crystal measurements. Changes
Bioorganic & medicinal chemistry, 21(5), 1305-1311 (2013-02-05)
Galactosyltransferases (GalTs) extend the glycan chains of mammalian glycoproteins by adding Gal to terminal GlcNAc residues, and thus build the scaffolds for biologically important glycan structures. We have shown that positively charged bivalent imidazolium salts in which the two imidazolium
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