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159042

Sigma-Aldrich

Luperox® P, tert-Butyl peroxybenzoate

98%

Synonym(s):

tert-Butyl peroxybenzoate, tert-Butyl perbenzoate

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About This Item

Linear Formula:
C6H5COOOC(CH3)3
CAS Number:
614-45-9
Molecular Weight:
194.23
Beilstein:
1342734
EC Number:
210-382-2
MDL number:
MFCD00008802
UNSPSC Code:
12352100
PubChem Substance ID:
24849787
NACRES:
NA.22

vapor density

6.7 (vs air)

vapor pressure

3.36 mmHg ( 50 °C)

Assay

98%

form

liquid

refractive index

n20/D 1.499 (lit.)

bp

75-76 °C/0.2 mmHg (lit.)

solubility

water: soluble 1.18 g/L

density

1.021 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)OOC(=O)c1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3

InChI key

GJBRNHKUVLOCEB-UHFFFAOYSA-N

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General description

tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane has been reported.

Application

Luperox was employed as polymerization and cross-linking catalyst. It was also was employed as initiator during:
  • grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene)
  • preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Signal Word

Danger

Hazard Statements

H242,H315,H317,H332,H410

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 2

Flash Point(F)

200.1 °F - closed cup

Flash Point(C)

93.4 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Jia-Jia Cao et al.
Chemical communications (Cambridge, England), 50(49), 6439-6442 (2014-04-05)
An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H bond functionalization under metal-free conditions.
Structural comparison of products from peroxide-initiated grafting of vinylsilane and silane-functionalized nitroxyl to hydrocarbon and polyolefin substrates.
Weaver JD, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 46(13), 4542-4555 (2008)
Chengguo Liu et al.
Polymers, 11(5) (2019-05-10)
New tung oil (TO)-based, unsaturated, co-ester (Co-UE) macromonomers bearing steric hindrance were synthesized by modifying a TO-based maleate (TOPERMA) monomer with an anhydride structure with hydroxyethyl methacrylate (HEMA) and methallyl alcohol (MAA), respectively. The obtained Co-UE monomers (TOPERMA-HEMA and TOPERMA-MAA)
Jingjing Xu et al.
ACS applied materials & interfaces, 3(7), 2410-2416 (2011-06-08)
Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD synthesis. Using TBPOB instead of
M Athar et al.
Carcinogenesis, 10(8), 1499-1503 (1989-08-01)
Humans are exposed to various peroxy and hydroperoxy compounds which are in use in the cosmetic, pharmaceutical and polymer industries and which are also generated as a result of the peroxidative metabolic conversion of certain lipids. This study was designed
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