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Propineb

PESTANAL®, analytical standard

Synonym(s):

Zinc propylenebis(dithiocarbamate)

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About This Item

Linear Formula:
[C5H8N2S4Zn]n
CAS Number:
Beilstein:
2360676
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

description

technical mixture

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

mol wt

Mw 289.78 g/mol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CC1CNC(=S)S[Zn]SC(=S)N1

InChI

1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2

InChI key

KKMLIVYBGSAJPM-UHFFFAOYSA-L

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General description

Propineb belongs to the dithiocarbamates (DTCs) class of fungicides, widely used in agriculture and horticulture. It has an additional advantage of low production cost, broad-spectrum of chemical and biological reactivity.

Application

Propineb may be used as an analytical reference standard for the quantification of the analyte in environmental samples and vegetable samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardEnvironment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Chronic 2 - STOT RE 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number

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Kelly Flampouri et al.
Talanta, 80(5), 1799-1804 (2010-02-16)
Two of the most important categories of pesticides used in agricultural practice are organophosphates and dithiocarbamates. Their extensive and inappropriate use has rendered their reliable monitoring at trace levels more and more necessary. This study presents the construction of a
M Yaldiz et al.
Clinical and experimental obstetrics & gynecology, 27(3-4), 235-237 (2001-02-24)
The dithiocarbamates are known to cause dermatitis, conjunctivitis, rhinitis, pharyngitis and bronchitis in humans. The experimental group received Propineb (obtained from Bayer) concentrations of 400 ppm in distilled water five days a week (treatment time three weeks) administered orally by
Marina Titlic et al.
The journal of headache and pain, 8(6), 345-347 (2007-12-13)
We report on headache caused by the pesticide Antracol Combi WP 76. A headache caused by handling of pesticides should be distinguishable from migraine and headaches from other causes. This 29-year-old woman, who handled pesticides, presented with very strong headache
Determination of propylenethiourea, the main metabolite of propineb, in tomato by HILIC-MS
Tolgyesi L, et al.
Chromatographia, 71(1), 75-80 (2010)
I Quinto et al.
Mutation research, 124(3-4), 235-240 (1983-12-01)
Propineb, a dithiocarbamate fungicide, was studied by using the sperm morphology assay in (C57BL6 male X C3H female) F1 mice. At all dose levels, no statistically significant increase in the percentage of sperm abnormalities was observed. Methyl methanesulfonate (MMS) and

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