- Synthesis and catalytic properties of mesoporous, bifunctional, gallium-niobium mixed oxides.
Synthesis and catalytic properties of mesoporous, bifunctional, gallium-niobium mixed oxides.
Chemical communications (Cambridge, England) (2010-08-18)
Chinmay A Deshmane, Jacek B Jasinski, Paul Ratnasamy, Moises A Carreon
PMID20714564
要旨
Thermally stable mesoporous Ga-Nb mixed oxides, active in both acid-catalysed and redox reactions have been synthesized via self-assembly hydrothermal assisted approach. Methyl oleate, a major component of biodiesels, undergoes double bond and skeletal isomerisation as well as dehydrogenation over these novel mesophases.