グレード
puriss.
品質
meets analytical specification of NF
濃度
30-32%
不純物
≤0.002% heavy metals (as Pb)
密度
1.206 g/mL at 20 °C (lit.)
微量陰イオン
chloride (Cl-): ≤200 mg/kg
sulfate (SO42-): ≤200 mg/kg
微量陽イオン
As: ≤1 mg/kg
Ca: ≤50 mg/kg
Cu: ≤5 mg/kg
Fe: ≤20 mg/kg
Na: ≤1000 mg/kg
SMILES記法
O[PH2]=O
InChI
1S/H3O2P/c1-3-2/h3H2,(H,1,2)
InChI Key
ACVYVLVWPXVTIT-UHFFFAOYSA-N
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詳細
Phosphinic acid is a reagent containing P-H bond. Phosphinic acids (phosphinates) are the derivatives of phosphinic acid H2P(O)(OH). Biochemical, biological, and medical applications of phosphinic acid compounds have been evaluated. Natural products containing carbon-phosphorus bonds (phosphonic and phosphinic acids) have wide applications in medicine and agriculture. Phosphinic acids have been synthesized via Michael addition of phosphonous acids as well as esters to activated conjugated systems. Phosphinic acid (Hypophosphorous acid) is an effective radical reducing agent for organic halides, thionoesters and isocyanides.
Preparation of phosphinic acids: Michael additions of phosphonous acids/esters to conjugated systems.
Thottathil JK, et al.
Tetrahedron Letters, 25(42), 4741-4744 (1984)
William W Metcalf et al.
Annual review of biochemistry, 78, 65-94 (2009-06-06)
Natural products containing carbon-phosphorus bonds (phosphonic and phosphinic acids) have found widespread use in medicine and agriculture. Recent years have seen a renewed interest in the biochemistry and biology of these compounds with the cloning of the biosynthetic gene clusters
Hypophosphorous acid and its salts: New reagents for radical chain deoxygenation, dehalogenation and deamination.
Barton DHR, et al.
Tetrahedron Letters, 33(39), 5709-5712 (1992)
M Collinsová et al.
Current medicinal chemistry, 7(6), 629-647 (2000-03-07)
This review summarizes our knowledge of biochemical, biological and medical applications and properties of phosphinic acid compounds. Phosphinic acid compounds (phosphinates) are derivatives of phosphinic acid H2P(O)(OH). The major attention of this article is focused on applications of phosphinates of
The invention of radical reactions. Part 32. Radical deoxygenations, dehalogenations, and deaminations with dialkyl phosphites and hypophosphorous acid as hydrogen sources.
Barton DHR, et al.
The Journal of Organic Chemistry, 58(24), 6838-6842 (1993)
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