793434

4-Tolyl-α-MIDA-boryl aldehyde

• 別名: (6-Methyl-4,8-dioxo-1,3,6,2-dioxazaborocan-2-yl)(4-methylphenyl)acetaldehyde
• 実験式（ヒル表記法）: C₁₄H₁₆BNO₅
• CAS番号: 1329422-56-1
• 分子量: 289.09
• MDL番号: MFCD27665011
• UNSPSCコード: 12352103
• PubChem Substance ID: 329768076
• NACRES: NA.22

特性

• フォーム: solid
• mp: 135-142 °C
• 官能基: aldehyde
• 保管温度: 2-8°C
• SMILES記法: O=C1OB(C(C2=CC=C(C)C=C2)C([H])=O)OC(CN(C)C1)=O
• InChI: 1S/C14H16BNO5/c1-10-3-5-11(6-4-10)12(9-17)15-20-13(18)7-16(2)8-14(19)21-15/h3-6,9,12H,7-8H2,1-2H3
• InChI Key: DCVSWHVQPHHNBM-UHFFFAOYSA-N

詳細

詳細

4-Tolyl-α-MIDA-boryl aldehyde is a-boryl aldehyde derivative. It can be synthesized from oxiranyl MIDA boronates, via rearrangement.[1]

アプリケーション

This boronic acid derivative is in a series of the first known stable α-boryl aldehyde species. Through the employment of the MIDA-protected boronic ester, this building block has been shown as a precursor to the synthesis of unnatural amino acids.

その他情報

Amphoteric Alpha-Boryl Aldehydes

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable