52738-U

Supelclean^™ PSA SPE Bulk Packing

pkg of 100 g

• Synonym(s): PSA SPE material (primary secondary amine)
• UNSPSC Code: 41115712
• NACRES: NB.21

Properties

• Agency: suitable for GB 5009.253-2016
• Quality Level: 100
• product line: Supelclean^™
• feature: endcapped
• packaging: pkg of 100 g
• extent of labeling: 8.4% C; 3.3% N loading
• technique(s): solid phase extraction (SPE): suitable
• surface area: 500 m²/g
• surface coverage: surface coverage 2.35 μmol/m²
• matrix: silica gel base material (irregularly shaped)
• matrix active group: ethylenediamine-N-propy bonding
• particle size: 50 μm
• pore size: 70 Å pore size
• pKa: (1) 10.1, (2) 10.9
• capacity: 0.98-1.05 meq/g capacity
• application(s): food and beverages
• separation technique: ion exchange; normal phase

Description

General description

Retention Mechanism: Normal-phase and anion-exchange
Sample Matrix Compatibility: Organic or aqueous solutions

• Polymerically bonded, ethylenediamine-N-propyl phase that contains both primary and secondary amines
• A weak anion exchanger with a pKa of 10.1 and 10.9
• Similar to aminopropyl SPE phases (NH₂) in terms of selectivity, but has a much higher capacity due to presence of secondary amine (0.98-1.05 meq/g)
• Strong affinity and high capacity for removing fatty acids, organic acids, and some polar pigments and sugars when conducting multi-residue pesticide analysis in foods
• Has been shown to significantly reduce matrix-enhancement effects encountered during the GC analysis of food products
• Tested for superior cleanliness using GC-FID and GC-MS
• Bidentate nature of ligand allows for chelation

Application

Supelclean^™ PSA SPE Bulk Packing may be used as a sorbent in the solid-phase dispersive extraction followed by single flow injection multi-commuted system/solid-surface fluorescence spectroscopic analysis of diphenylamine in apples and pears.

Legal Information

Supelclean is a trademark of Sigma-Aldrich Co. LLC

Safety Information

• Pictograms: GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H317,H318,H373
• Precautionary Statements: P260 - P272 - P280 - P302 + P352 - P305 + P351 + P338 - P314
• Hazard Classifications: Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Inhalation
• Target Organs: respiratory tract irritation
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable