M1014
Methyl 3-amino-3-deoxy-α-D-mannopyranoside hydrochloride
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form
solid
storage temp.
2-8°C
SMILES string
Cl.COC1OC(CO)C(O)C(N)C1O
InChI
1S/C7H15NO5.ClH/c1-12-7-6(11)4(8)5(10)3(2-9)13-7;/h3-7,9-11H,2,8H2,1H3;1H
InChI key
UMFRURBOSLCTIW-UHFFFAOYSA-N
Application
Methyl 3-amino-3-deoxy-α-D-mannopyranoside hydrochloride has been used in a study to assess the importance of the nitrogen protecting group on stereoselectivity.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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The Journal of organic chemistry, 72(14), 5183-5192 (2007-06-15)
The highly stereocontrolled synthesis of the 3-amino-3-deoxy-beta-mannopyranosides is achieved by means of thioglycoside donors protected with a 4,6-O-benzylidene or alkylidene acetal and a benzylidene imine group. Among the various nitrogen protecting groups investigated only the Schiff's base was found to
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