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Safety Information

C6003

Sigma-Aldrich

Chlorophyllin sodium copper salt

commercial grade, powder

Synonym(s):

Chlorophyllin, coppered trisodium salt

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¥5,960
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5 G
¥5,960
25 G
¥16,100
100 G
¥48,500

About This Item

Empirical Formula (Hill Notation):
C34H31CuN4Na3O6
CAS Number:
11006-34-1
Molecular Weight:
724.15
EC Number:
234-242-5
MDL number:
MFCD28016032
UNSPSC Code:
12171500
PubChem Substance ID:
24892826
NACRES:
NA.47

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Product Name

Chlorophyllin sodium copper salt,

form

powder

technique(s)

microbe id | staining: suitable

color

black
 green to very dark green

solubility

H2O: 100 mg/mL, dark green

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

2-8°C

SMILES string

[Na+].[Na+].[Na+].CCc1c(C)c2cc3c(C=C)c(C)c4cc5nc(C(CCC([O-])=O)C5C)c(CC([O-])=O)c6c(C([O-])=O)c(C)c(cc1n2)n6[Cu]n34

InChI

1S/C34H36N4O6.Cu.3Na/c1-7-19-15(3)23-12-25-17(5)21(9-10-29(39)40)32(37-25)22(11-30(41)42)33-31(34(43)44)18(6)26(38-33)14-28-20(8-2)16(4)24(36-28)13-27(19)35-23;;;;/h7,12-14,17,21H,1,8-11H2,2-6H3,(H5,35,36,37,38,39,40,41,42,43,44);;;;/q;+2;3*+1/p-5

InChI key

HWDGVJUIHRPKFR-UHFFFAOYSA-I

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Application

Chlorophyllin sodium copper salt has been used to study the effect of chlorophyllin against radiation-induced hematopoietic syndrome.[1] It has been used to study the effect of chlorophyllin on the excretion of PhIP (2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine) and its metabolites into the breast-milk of lactating rats.[2]

Biochem/physiol Actions

Chlorophyllin is a water soluble derivative of chlorophyll. It has chemopreventive properties and forms a non-covalent complex with many mutagenic/carcinogenic molecules. The complex formation reduces absorption or allows excretion of the mutagenic/carcinogenic molecules.[2] Chlorophyllin also exhibits antioxidant, antiapoptotic and immunostimulatory effects. It provides benefits, such as prevention of body odor and increased wound healing.[1]

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

C6003-BULK:
C6003-25G:4548173948102
C6003-5G:4548173948119
C6003-100G:4548173948096
C6003-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP2527
SHBQ0233
SHBQ0595
SHBN9046
SHBM8996

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Jun Zhang et al.
The Analyst, 137(18), 4287-4294 (2012-08-02)
The human hepatoma 3B cell line was chosen as an experimental model for in vitro test of drug screening. The drugs included chlorophyllin and its derivatives such as fluo-chlorophyllin, sodium copper chlorophyllin, and sodium iron chlorophyllin. The 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-tetrazolium bromide (MTT)
Yan-lin Zhang et al.
Zhonghua nei ke za zhi, 51(6), 466-470 (2012-09-05)
To investigate whether chlorophyllin could protect human umbilical vein endothelial cell (HUVEC) against oxidative damage by inducing the expression of heme oxygenase-1 (HO-1) and to explore the underlying mechanism. The cellular protection of chlorophyllin against oxidative damage was detected by
Distribution and metabolism of 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP) in female rats and their pups at dietary doses.
Mauthe RJ, et al.
Carcinogenesis, 19, 919-924 (1998)
Wei Li et al.
Nanomedicine (London, England), 7(3), 383-392 (2012-03-06)
How to overcome insufficient drug release is an important issue in the drug-delivery system. Here, a novel temperature and UV dual-control poly(N-isopropylacrylamide [PNIPAM]-co-chlorophyllin) nanogel was prepared via the surfactant-free emulsion polymerization. The introduction of hydrophilic chlorophyllin to the PNIPAM chain
Maria Rosaria Grossi et al.
Toxicology letters, 214(3), 235-242 (2012-09-19)
Chlorophyllin (CHL), a water soluble derivative of chlorophyll has been shown to have both anticarcinogenic and antigenotoxic properties. We evaluated the protective effects of CHL (25μM in vitro, 4 and 100mg/kg. b.w.) on the clastogenic action of two model carcinogens
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